Manganese benzyl sulfonates

Benzylic Manganese Halides, Sulfonates, and Phosphates Preparation, Coupling Reactions, and Applications in New Reactions... [Pg.320]

Considering the high reactivity of the active manganese (Mn ) metal prepared by the Rieke method and the exceptional tolerance to a wide range of functionality in the organic moiety, we explored the possibility of the direct oxidative addition to a variety of carbon-oxygen bonds. Our first approach employed benzyl sulfonates. This was expanded to functionalized and... [Pg.324]

Table 8.7 Cross-coupling reaction of benzylic and functionalized benzylic manganese sulfonates. [Pg.317]

Preparation and Coupling Reactions of Benzylic Manganese Sulfonates and Phosphates... [Pg.322]

Additives used in final products Fillers calcium carbonate, calcium hydroxide, calcium oxide, carbon black, polymeric beads, polystyrene particles, zinc oxide Plasticizers 1-isobutyrate benzyl phthalate, 2,2,4-tri-methyl-1,3-pentanediol, alkyl sulfonic acid esters of phenol and/or cresol, benzyl butyl phthalate, chlorinated paraffins, hydrogenated perphenyl, isooctyl benzyl phthalate Curatives metal peroxides, oxy salts (e.g., dioxides of lead, manganese, calcium, etc.) ... [Pg.578]