Magnetic moment, ferromagnetic

In contradistinction to this, weak ferromagnetism has been observed in a number of chloro and bromo complexes of the type M2[CrX4] (M = a variety of protonated amines and alkali metal cations, X = Cl, Br), which are analogous to previously known copper(II) complexes (p. 1192). They have magnetic moments at room temperature in the region of 6BM (compared... 

Figure 1 Energy difference between the possible antiferromagnetic states and the ferromagnetic one as the function of Au concentration in the substrate. and J, refer to the orientation of the magnetic moments in a layer. The substrate is assumed to be on the left hand side.

The muffin-tin potential around each atom in the unit cell has been calculated in the framework of the Local-Spin-Density-Approximation using the ASW method. The ASW method uses the atomic sphere approximation (ASA), i.e. for each atom a sphere radius is chosen such that the sum of the volumes of all the overlapping spheres equals the unit cell volume. The calculation yields the expected ferromagnetic coupling between Cr and Ni. From the self-consistent spin polarized DOS, partial and total magnetic moment per formula unit can be computed. The calculated total magnetic moment is 5.2 pg in agreement with the experimental value (5.3 0.1 e calculations presented here have been performed... 

If a paramagnetic salt is cooled, eventually a temperature is reached where the magnetic moments of the electrons line up. This temperature is known as the Curie point or the Neel point, depending upon whether the spins line up parallel below this temperature as in (b), with the moments pointing in the same direction to reinforce one another and produce ferromagnetism, or the moments line up in opposite directions as in (c) so that they cancel and antiferromagnetism occurs. 

Figure 5b. Variation in the magnetic properties of metal clusters are investigated by measuring the depletion of a highly collimated cluster beam by an inhomogeneous magnetic field. Fe clusters and their oxides (FexO and Fex02) at several applied fields. The uniform depletion of Fe clusters indicates that their magnetic moments increase approximately linearly with number of atoms, as would be anticipated for incipient ferromagnetic iron. Unexpected, however, is the much larger depletion of iron oxide clusters.

Figure 2. Plot of relative magnetization, a/Os ns a function of H/T. (a) A paramagnetic system Is characterized by an effective magnetic moment, with a Bohr Magneton number vlO per Ion, and by the absence of hysteresis. Paramagnetic saturation occurs at very high "H/T" == 10 Oe K"l. (b) l.angevln curve for S.P. clusters, (c) Part of a ferromagnetic hysteresis curve.

When a magnetic field, B, is applied to a ferromagnetic or ferrimagnetic particle with magnetic moment, p, the magnetic energy has a contribution from the Zeeman term... 

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