Magnesium sulfamate

Calcium sulfamate and magnesium sulfamate are used effectively as a stiffening promoter of concrete and hydrauHc cement (see Cement). 

Calcium/magnesium carbonate/hydroxide and calcium phosphate can be removed by using 5 to 15% hydrochloric acid at 140 to 150 °F, by recirculating tetrasodium EDTA at 200 to 300 °F, or by 7 to 10% sulfamic acid at 140 to 150 °F. The temperature may need to be a little higher to start the dissolution process. 

C. Sulfamates prepared from weak bases form acidic solutions, whereas those prepared from strong bases produce neutral solutions. The pH of 5 wt % solution of ammonium sulfamate is 5.2. Crystals of ammonium sulfamate deliquesce at relative humidity of 70% and higher. Both ammonium sulfamate [7773-06-0] and potassium sulfamate [13823-30-2] hbemte ammonia at elevated temperatures and form the corresponding imidodisulfonate (12). Inorganic sulfamates are quite water-soluble, except for the basic mercury salt. Some relative solubilities of sulfamates at 25°C in 100 g of water are ammonium, 103 g sodium, 106 g magnesium, 119 g calcium, 67 g barium, 34.2 g zinc, 115 g and lead, 218 g. The properties of a number of sulfamates may be found in the literature (see Table 5). 

Fertilizer - [AMMONIUMCOMPOUNDS] (Vol2) -ammoniumsulfate [AMMONIUMCOMPOUNDS] (Vol2) -castor pomace as [CASTOR OIL] (Vol 5) -iron compounds m [IRON COMPOUNDS] (Vol 14) -from lignite and brown coal [LIGNITE AND BROWN COAL] (Vol 15) -lime fillers [LIME AND LIMESTONE] (Vol 15) -magnesiumnitrate [MAGNESIUM COMPOUNDS] (Vol 15) -molybdenum compounds as [MOLYBDENUMAND COMPOUNDS] (Vol 16) -phosphorus precipitator dust as [PHOSPHORUS] (Vol 18) -raw material for [SULFAMIC ACID AND SULF AMATES] (Vol 23) -sodium nitrate as [SODIUM COMPOUNDS - SODIUM NITRATE] (Vol 22) -vanadium as by-product [VANADIUM AND VANADIUM ALLOYS] (Vol 24)... 

MAGNESIUM NITRATE or MAGNESIUM(H) NITRATE (10377-60-3) A powerful oxidizer. Reacts violently with dimethylfoimamide, reducing agents, combustible materials, fuels, organic substances, metal powders, potassium hexanitrocobalite(III) (C.I. pigment yellow), sodium acetyUde, and easily oxidizable matter. Incompatible with aluminum, ammonium hexacyanoferrate(II), ferf-butylhydroperoxide, citric acid, ethanol, ferrocyanides, hydrazinium perchlorate, isopropyl chlorocarbonate, metal phosphinates, nitrosyl perchlorate, organic azides, phosphorus, sodium thiosulfate, sulfamic acid, thiocyanates, tin(II) fluoride, and many other substances. 

The direct copper-catalyzed iodosyl-mediated nitrogen transfer to olefins compares with the parent rhodium-catalyzed process that is made possible by the combination of iodosylbenzene diacetate, magnesium oxide, and sulfamates. Other recent promising nitrene transfer methods involve the bromine-catalyzed aziridination of olefins using chloramine-T and the direct electrochemical aziridination with TV aminophthalimide. ... 

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