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M-Toluic acid

A similar sequence starting with m-toluic acid then gave the -toluate. [Pg.38]

Show how m-toluic acid could be formed from the abstraction reaction of OH with m-xylene (Table 9.22). [Pg.423]

Sam Zard of the Ecole Polytechnique in Paliseau has developed elegant and affordable free-radical methods for C-C bond construction. In the context of the total synthesis of pleuromutilin, he recently reported (Organic Lett. 5 325, 2003) that the free radical cyclization of 12 proceeded smoothly to give the eight-membered ring product 13. The ketone 12 is easily prepared from m-toluic acid. It is a tribute to the efficacy of the cyclization procedure that the conformation drawn, the conformation required for cyclization, is the less stable chair available to 12. [Pg.129]

Allyl phenyl ether Benzaldehyde o-Cresol m-Toluic acid... [Pg.111]

Amino-benzyl alcohol m-Toluic acid m-Anisic acid... [Pg.37]

Over nickel catalysts, aromatic carboxylic acids can be hydrogenated without difficulty as their sodium salts. Thus, e>-179 and m-toluic acids,180 m-hydroxybenzoic acid,181 and tetrephthalic acid182 were hydrogenated to the corresponding saturated acids in high yields over Raney Ni at elevated temperatures and pressures. Examples are shown in eqs. 11.47 and 11.48. o-Toluic acid and terephthalic acid afforded the trans acids predominantly under these conditions. [Pg.454]

BROMO-3-METHYLBENZOIC ACID (m-Toluic acid, 2-bromo-)... [Pg.11]

DIETHYLTOLUAMIDE NJSi-DIETHYL-m-TOL-UAMIDE ENT 20,218 ENT 22,542 FLYPEL METADELPHENE 3-METHYL-N4SI-DIETHYLBENZ-AAHDE MGK DIETHYLTOLUAMIDE NAUGATUCK DET OFF REPEL REPPER-DET REPUDIN-SPECIAL m-TOLUIC ACID DIETHYLAMIDE... [Pg.498]

Chemical Name m-toluic acid, 3-methyl benzoic acid... [Pg.486]

FIGURE 13.1.2.3.1 Logarithm of mole fraction solubility (In x) versus reciprocal temperature for 3-methy I benzoic acid (m-toluic acid). [Pg.488]

See other pages where M-Toluic acid is mentioned: [Pg.293]    [Pg.509]    [Pg.392]    [Pg.797]    [Pg.144]    [Pg.2279]    [Pg.122]    [Pg.1157]    [Pg.1442]    [Pg.1540]    [Pg.223]    [Pg.217]    [Pg.103]    [Pg.404]    [Pg.248]    [Pg.193]    [Pg.343]    [Pg.387]    [Pg.190]    [Pg.261]    [Pg.600]    [Pg.1348]    [Pg.1348]    [Pg.110]    [Pg.183]    [Pg.2279]    [Pg.145]    [Pg.1348]    [Pg.1348]    [Pg.774]    [Pg.248]    [Pg.435]    [Pg.486]    [Pg.486]    [Pg.488]    [Pg.237]   
See also in sourсe #XX -- [ Pg.774 ]

See also in sourсe #XX -- [ Pg.56 , Pg.86 ]

See also in sourсe #XX -- [ Pg.56 , Pg.86 ]

See also in sourсe #XX -- [ Pg.754 ]

See also in sourсe #XX -- [ Pg.371 ]



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