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M-Methoxyphenol

Xylamidine (87) is an amidine which serves as a serotonin inhibitor. This agent is prepared by alkylation of m-methoxyphenol with a-chloropropio-nitrile, KI and potassium carbonate in methylethyl ketone to give 85, which is in turn reduced with... [Pg.54]

This pK a is higher than would be anticipated for ortho- and meta- substituted phenols since the o meth-oxyphenol has a pK a of 9.98, m-methoxyphenol a pK a of 9.65 and resorcinol a pK a of F.81 (13). A molecular model of the drug shows that the free rotation of the phenolic hydrogen is hindered by the A -hydrogen and can explain a9-tetrahydrocannabinol s higher pK a. Of course, if solvated dimers, trimers, etc., exist with hydrophobic bonding, the observed pK a could be a hybrid pK a for a solution of such polymers. [Pg.17]

SYNS m-GUAIACOL m-HYDROXYANISOLE 3-HYDROXYANISOLE m-METHOXYPHENOL 3-METHOXYPHENOL RESORCINOL METHYL ETHER... [Pg.1209]

METHOXYPHENOL see MFC700 m-METHOXYPHENOL see REF050 o-METHOXYPHENOL see GKIOOO p-METHOXYPHENOL see MFC700... [Pg.1765]

The semi-methylation of resorcinol with dimethyl sulfate leads to m-methoxyphenol (45%). ... [Pg.566]

Other aryl fluoroalkanesulfonates besides trifluoromethanesulfonyl esters of phenols can be reduced to arenes. Moreover, the preparation of such esters and their reduction may be carried out in one pot . A mixture of m-methoxyphenol, perfluorooctanesulfonyl fluoride, triethylamine, dimethylformamide, for-... [Pg.911]

Biphenyl Dimethyl methyl m-Methoxyphenol Stearic acid... [Pg.406]

Anisole was hydroxylated by the ferrous ion-oxygen system in the presence of increasing amounts of added ferric ions. This resulted in a decrease rather than an increase in the proportion of m-methoxyphenol (Table XI). [Pg.268]

Derivatives of tetrafluoroiodobenzene react with terminal alkynes in the presence of a palladium-copper(I) iodide catalyst by displacement of the iodine atom (e.g. equation 7). m-Methoxyphenol condenses with phenylacetylene in the presence of the sulphonyl fluoride 54 and bis(triphenylphosphine)palladium(II) chloride to give m-methoxy-diphenylacetylene (equation 8). ... [Pg.293]


See other pages where M-Methoxyphenol is mentioned: [Pg.685]    [Pg.998]    [Pg.979]    [Pg.998]    [Pg.685]    [Pg.685]    [Pg.778]    [Pg.1005]    [Pg.58]    [Pg.93]    [Pg.103]    [Pg.158]    [Pg.164]    [Pg.171]    [Pg.286]    [Pg.1310]    [Pg.196]    [Pg.1310]    [Pg.778]    [Pg.719]    [Pg.685]    [Pg.944]    [Pg.735]    [Pg.735]    [Pg.91]    [Pg.101]    [Pg.156]    [Pg.169]    [Pg.173]    [Pg.208]    [Pg.290]    [Pg.685]    [Pg.944]    [Pg.33]    [Pg.124]    [Pg.143]    [Pg.207]    [Pg.300]    [Pg.310]    [Pg.322]   
See also in sourсe #XX -- [ Pg.354 ]




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Methoxyphenols

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