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Lithium dialkylcuprates enolate synthesis

The reduction of enol dialkylphosphate esters of ketones to alkenes has been known for some time recent work has now shown that the enolate oxygen atom in sterically unhindered enol diphenylphosphate esters can be replaced by an alkyl group using a lithium dialkylcuprate (Scheme 36), extending the scope of the reaction to a versatile synthesis of trisubstituted double bonds. [Pg.96]


See other pages where Lithium dialkylcuprates enolate synthesis is mentioned: [Pg.131]    [Pg.8]    [Pg.131]    [Pg.438]    [Pg.5]   
See also in sourсe #XX -- [ Pg.3 , Pg.8 ]

See also in sourсe #XX -- [ Pg.8 ]

See also in sourсe #XX -- [ Pg.3 , Pg.8 ]




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Dialkylcuprates

Enol synthesis

Enolate lithium

Enolate synthesis

Enolates lithium

Lithium dialkylcuprate

Lithium dialkylcuprates

Lithium enolates synthesis

Lithium synthesis

Synthesis enolates

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