Liquids powder wetting

This description is traditional, and some further comment is in order. The flat region of the type I isotherm has never been observed up to pressures approaching this type typically is observed in chemisorption, at pressures far below P. Types II and III approach the line asymptotically experimentally, such behavior is observed for adsorption on powdered samples, and the approach toward infinite film thickness is actually due to interparticle condensation [36] (see Section X-6B), although such behavior is expected even for adsorption on a flat surface if bulk liquid adsorbate wets the adsorbent. Types FV and V specifically refer to porous solids. There is a need to recognize at least the two additional isotherm types shown in Fig. XVII-8. These are two simple types possible for adsorption on a flat surface for the case where bulk liquid adsorbate rests on the adsorbent with a finite contact angle [37, 38]. 

Solids handling frequently has the potential for dusting, which can lead to potential health and explosion hazards. Handling solids in the form of larger particle size granules or pellets rather than a fine powder reduces the potential for worker exposure. Worker exposure hazards are reduced by formulating dyes as liquids or wet pastes rather than dry solids or powders (Burch, 1986). 

Oxide Powder liquid, gcm Wet compressive Strain at failure, % True porosity, %... 

Percent chrysotile asbestos in bulk samples may be measured by X-ray powder diffraction (NIOSH Method 9000, 1984) sample dust grinded under liquid N2 wet sieved through 10-mm sieve sieved material treated with 2-propanol agitated in an ultrasonic bath filtered on a silver filter measured by XRD, using a Cu target X-ray tube. 

When a powder is immersed in a liquid and wetting takes place, heat is given off. The heat of wetting for various powder surfaces is given in Table 9.4. 

A low surface tension value correlates with a small contact angle. The binder with the smaller contact angle has improved spreadabiiity and can wet powders more effectively (65,84). A surfactant can also be added to the binder solution to improve wettability, especially for hydrophobic powders, and functions to lower both the surface tension as well as the contact angle of the liquid. If the contact angle, 6, is less than 90, then the powder wetting is spontaneous. However, if the contact angle is closer to 180 then the powder would be considered unwettable by the liquid. The pore space within a particle assembly can be simplistically considered as a model capillary. The capillary pressure, Pc, of a liquid is related to the surface tension by the following equation ... 

The adsorption of surfactants at the solid/liquid (S/L) interface determines their efficiency in powder wetting and dispersion. A reduction of the S/L interfacial tension by surfactant adsorption leads to a reduction of the contact angle, which in turn ensures complete wetting of the powder by the Hquid. In addition, the... 

For agglomerates (as represented in Figure 11.2), which are found in aU powders, wetting of the internal surface between the particles in the structure requires liquid penetration through the pores. Assuming that the pores behave as simple capillaries of radius r, Ap is given by the following equation ... 

Most processes of powder wetting operate under dynamic conditions, and improvements in their efficiency require the use of surfactants that lower the liquid surface tension Yiy under these circumstances. The interfaces involved (particles separated from aggregates or agglomerates) are freshly formed and have only a small effective age of some seconds, or even less than a millisecond. 

Binder liquid should wet the solid particles and not the interior walls or the mixing tools of the equipment. If parts of the mixer are wetted, build-up occurs which is difficult to remove. Different spray patterns are available with commercially available single or two phase nozzles (Fig. 7.22c and 7.23) and a suitable pattern should be selected to assure that liquid impinges only on the moving powder. Since the spray pattern depends critically on the cleanliness of the orifice area, as mentioned before, nozzles must be drip free and installed such that they remain clean or are blown free by the action of atomizing gas. This is particularly important for low capacity nozzles which are often preferred because the binder liquid should be always completely ab-... 

Where the parameter R is an averaged value of the apparent capillary radius of the thin porous layer (29). However, as shown in (33-35), Eq. [16] is valid only if a precursor duplex liquid (ilm is pre.sent ahead of the penetrating front of a liquid completely wetting the solid surface. Thus, from this equation it is clearly seen that the surface free energy of the substrate is not related to the rate of penetration of the liquid. Nevertheless, Eq. [16] is very useful for the determination of the R parameter of glass plates covered with the powder of the solid tested. Liquids most suitable for this purpose are the i-alkanes. like n-octane or n-decane. 

The heat of immersion is measured calorimetrically with finely divided powders as described by several authors [9,11-14] and also in Section XVI-4. Some hi data are given in Table X-1. Polar solids show large heats of immersion in polar liquids and smaller ones in nonpolar liquids. Zetdemoyer [15] noted that for a given solid, hi was essentially a linear function of the dipole moment of the wetting liquid. 

High Surface Sodium. Liquid sodium readily wets many soHd surfaces. This property may be used to provide a highly reactive form of sodium without contamination by hydrocarbons. Powdered soHds having a high surface area per unit volume, eg, completely dehydrated activated alumina powder, provide a suitable base for high surface sodium. Other powders, eg, sodium chloride, hydride, monoxide, or carbonate, can also be used. 

---