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Linear Recursive Methods - Kekule Structure Counting

2 Linear Recursive Methods - Kekule Structure Counting. - A rather [Pg.64]

There is another neat scheme (based on the linear recursion) applicable for hand computation on polyhex benzenoids of up to a dozen or so hexagonal rings. This John-Sachs scheme is based on a one-to-one correspondence between Kekule structures and sets of mutually self-avoiding directed walks on the graph, and indeed this correspondence was (in a special context) utilized in a statistical mechanical context in modelling collections of partly disordered polymer chains. [Pg.65]

The consideration of the sets of mutually self-avoiding walkers has a wider impact in revealing a fundamental invariant (the number of walkers) which turns out to be important in transfer-matrix solutions, as applied to polymer graphs extending even to the two-dimensional limit (as discussed in the next subsection). Also this invariant, which may also be described as an order, has physical implications.  [Pg.67]

Overall the general recursion of eqn. (2) is applicable beyond the case of Kekule structures here elaborated for illustration. The related so-called conju-gated-circuit method turns out to have quite neat (related) linear re-cursions. Generally many sub-graph enumeration problems turn out to be of a linear recursive nature. [Pg.67]


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Recursion method

Recursion method structure

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