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Leaving group nitrogen

The nucleophile in the S.v2 reactions between benzyldimethylphenylammonium nitrate and sodium para-substituted thiophenoxides in methanol at 20 °C (equation 42) can exist as a free thiophenoxide ion or as a solvent-separated ion-pair complex (equation 43)62,63. The secondary alpha deuterium and primary leaving group nitrogen kinetic isotope effects for these Sjv2 reactions were determined to learn how a substituent on the nucleophile affects the structure of the S.v2 transition state for the free ion and ion-pair reactions64. [Pg.941]

TABLE 14. The secondary alpha deuterium kinetic isotope effects and primary leaving group nitrogen kinetic isotope effects for the free ion and ion-pair S 2 reactions between benzyldimethylphenylammonium nitrate and para-substituted thiophenoxide ions in methanol at 20 °C... [Pg.942]

Table 23 The secondary a-deuterium and leaving group nitrogen KIEs for the Sn2 reactions between the solvent-separated sodium thiophenoxide ion pair and benzyldimethylphenylam-monium nitrate in DMF at 0°C and in methanol at 20.000 0.002°C... Table 23 The secondary a-deuterium and leaving group nitrogen KIEs for the Sn2 reactions between the solvent-separated sodium thiophenoxide ion pair and benzyldimethylphenylam-monium nitrate in DMF at 0°C and in methanol at 20.000 0.002°C...
See other pages where Leaving group nitrogen is mentioned: [Pg.267]    [Pg.941]    [Pg.945]    [Pg.946]    [Pg.267]    [Pg.77]    [Pg.267]    [Pg.274]    [Pg.278]    [Pg.279]    [Pg.267]    [Pg.260]    [Pg.261]    [Pg.365]    [Pg.288]    [Pg.168]    [Pg.174]    [Pg.195]    [Pg.356]    [Pg.283]   
See also in sourсe #XX -- [ Pg.100 , Pg.104 , Pg.107 , Pg.114 , Pg.121 , Pg.123 , Pg.169 , Pg.305 ]

See also in sourсe #XX -- [ Pg.100 , Pg.104 , Pg.107 , Pg.114 , Pg.121 , Pg.123 , Pg.169 , Pg.305 ]

See also in sourсe #XX -- [ Pg.2 , Pg.848 ]



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Leaving groups nitrogen of diazonium ions

Nitrogen Group

Nitrogen, electron structure leaving group

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