Lead bromate periodate

Lead acetate-lead bromate, 1540 Lead(II) chlorite, 4102 Mercury(II) bromate, 0270 Potassium bromate, 0255 Potassium chlorate, 4017 Potassium periodate, 4620 Silver bromate, 0007... 

Dialdehyde starch Tetraethyl lead Tetramethyl lead Adiponitrile Fluorocarbons Potassium perchlorate Sodium perchlorate [ Potassium bromate i Sodium bromate I Periodates j... 

Figure 7.5 Simulation of the bromate-chlorite-iodide reaction, (a) With an error tolerance of lO", chaotic behavior is obtained, (b) Tightening the tolerance to 10" leads to the correct result, periodic behavior. (Adapted from Citri and Epstein, 1988.)...

Rate-determining steps leading to I(IV) and I(III) are postulated, with subsequent rapid reduction of intermediate iodine species. An induction period followed by oxidation of the [Fe(phen)3] complex is a feature of the reaction of that complex with bromate ions. The rates of the corresponding reactions with CI2 and affected by Cl", Br", or hydrogen ion. The oxidations occur via the one-electron transfer steps and an analysis of the data and those for other metal ion reductants has been made using a Marcus theory approach. The kinetics of the peroxodisulfate oxidation of two [Fe(II)(a-diimine)3] complexes have been investigated in binary aqueous-solvent mixtures.The rate data have been dissected into initial and transition state energies. Comparisons between the relative contributions to these parameters for redox and substitution reactions remain a topic of interest. 

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