Layered Materials by Design

Biradha, Kumar, Layered Materials by Design 2D Coordination Polymeric Networks Containing Large Cavities/Channels, 1, 211. 

V. A. Russell, M. C. Etter, M. D. Ward, "Layered materials by molecular design structural enforcement by hydrogen bonding in guanidinium alkane- and arenesulfo-nates , J. Am. Chem. Soc 1994,116,1941-1952. 

Russell. V.A. Etter, M.C. Ward. M.D. Layered materials by molecular design — Stmctural enforcement by hydrogen-bonding in guanidiniura alkanesulfonate and arenesulfonate. J. Am. Chem. Soc. 1994. 116 (5). 1941-1952. 

Successive H-bond urea self-assembly of 4 and sol-gel transcription steps yield preferential conduction pathways within the hybrid membrane materials. Crystallographic, microscopic and transport data confirm the formation of self-organized molecular channels transcribed in solid dense thin-layer membranes. The ionic transport across the organized domains illustrates the power of the supramolecular approach for the design of continual hydrophilic transport devices in hybrid membrane materials by self-organization (Figure 10.8) [42-44]. 

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