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L-hexyl-3-methylimidazolium bis

Whereas, Goharshadi et al. [16] have synthesized the ZnO nanoparticles of 60 nm (Fig. 8.4.) using a room temperature ionic liquid, l-hexyl-3-methylimidazolium bis (trifluoromethylsulfonyl)imide, Formation of ZnO was not observed when the ionic liquid was replaced by water. Also, in the absence of ultrasound, formation of ZnO was not observed which is very similar to the one as proposed in the previous case of ZnO dendritic nanostructures. [Pg.196]

Letcher, T.M. et al.. Activity coefficients at infinite dilution measurements for organic solutes in the ionic liquid l-hexyl-3-methylimidazolium bis(trifluoro methylsulfonyl)-imide using glc at T = (298.15, 303.15 and 308.15) K, /. Chem. Thermodyn., i7, 1327, 2005. [Pg.70]

D. (2006) Thermodynamic properties of mixtures containing ionic liquids. 8. activity coefficients at infinite dilution of hydrocarbons, alcohols, esters, and aldehydes in l-Hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide using gas-liquid chromatography. Chem. Eng. Res. Des., 51 (2), 434-437. [Pg.206]

The phase behaviours of binary and ternary ionic liquid mixtures with carbon dioxide,organics " and water " have been determined using COSMO-RS. In the COSMO-RS framework, ionic liquids are considered to be completely dissociated into cations and anions. Ionic liquids are thus taken as an equimolar mixture of two distinct ions, which contribute as two different compounds. Because ionic liquids only dissociate in the presence of strongly polar substances, the COSMO-RS prediction of the phase behaviour of ionic liquid systems with polar compounds (water and alcohols) is more accurate than that of ionic liquid systems with nonpolar compounds (carbon dioxide and organics). Especially the COSMO-RS prediciton of the solubility of (relatively nonpolar) carbon dioxide in ionic liquids shows considerable deviations ( 15 %) from experimental values. lUPAC Technical Reports document the measurements of the thermodynamic and thermophysical properties of l-hexyl-3-methylimidazolium bis [(trifluoromethyl)sulfonyl]amide and the recommended values. ... [Pg.383]

Fig. 9 Pair-pair radial distribution functions of different solutes in different ionic liquid solutions. Solvents A l-butyl-3-methylimidazolium hexafluorophos-phate B l-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide C tri-hexyl(tetradecyl)phosphonium bis(trifluoromethanesulfonyl)imide. Solutes ... Fig. 9 Pair-pair radial distribution functions of different solutes in different ionic liquid solutions. Solvents A l-butyl-3-methylimidazolium hexafluorophos-phate B l-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide C tri-hexyl(tetradecyl)phosphonium bis(trifluoromethanesulfonyl)imide. Solutes ...
Harris KR, Kanakubo M, Woolf LA (2007) Temperature and pressure dependence of the viscosity of the ionic liquids l-hexyl-3-methylimidazolium hexafluorophosphate and 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide. J Chem Eng Data 52 1080-1085... [Pg.211]

The ionic liquid l-n-hexyl-3-methylimidazolium bis(trifiuorosulfonyl)imide, [hmim] [TfaN], was synthesized and characterized using standard procedures [17-19] at the University of Notre Dame. The ionic liquid l-(3-aminopropyl)-3-methylimidazolium bis(trifiuoromethylsulfonyl)imide, [H2NC3H5mim][Tf2N], was also synthesized and characterized at the University of Notre Dame [20]. [Pg.189]

Figure 2 Sample of the ionic liquid l-w-hexyl-3-methylimidazolium bis(trifluorome-thylsulfonyl)imide made in the laboratory of Joan Brennecke at the University of Notre Dame. This ionic liquid is clear and stays liquid well below room temperature. Figure 2 Sample of the ionic liquid l-w-hexyl-3-methylimidazolium bis(trifluorome-thylsulfonyl)imide made in the laboratory of Joan Brennecke at the University of Notre Dame. This ionic liquid is clear and stays liquid well below room temperature.
Absorption of Water in the Ionic Liquid l-t -Hexyl-3-methylimidazolium bis(trifluoro-... [Pg.490]

Modified graphene oxide was prepared using alkyl imidazol-ium ionic liquids (l-butyl-3-methylimidazolium tetrafluoroborate, l-butyl-3-methylimidazolium hexafluorophosphate and l-hexyl-3-methyhmidazolium bis(trifluoromethylsulfonyl) amide via an epoxide ring-opening reaction, cation-p stacking, or van der Waals interactions, with modified graphene exfoliated from a graphite rod by a moderate electrochemical method as a a comparative material (3). [Pg.159]

Beigi AAN, Abdouss M, Yousefi M, Pourmortazavi AM, Vahid A (2013) Investigation on physical and electrochemical properties of three imidazolium based ionic liquids (l-hexyl-3-methylimidazolium tetrafluoroborate, l-ethyl-3-methylimidazolium bis(trifluoromethyl-sulfonyl) imide and l-butyl-3-methylimidazolium methylsulfate). J Mol Liq 177 361-368... [Pg.202]

Klomfar J, Souckova M, Patek J (2014) Low temperature densities from (218 to 364) K and up to 50 MPa in pressure and surface tension for Trihexyl(tetradecyl)phosphonium Bis (trifluoromethylsulfonyl)imide and dicyanamide and l-Hexyl-3-methylimidazolium hexafluorophosphate. J Chem Eng Data 59 2263-2274... [Pg.205]


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1-Hexyl-3-methylimidazolium

Bis- -hexyl

Hexyl

L- -3-methylimidazolium

Methylimidazolium

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