L 10- decane

N, N1 -dibexanoyl-4 nitraza-l, 7 -beptanediamine N, N -dipentanoyl-4, 7-dinitraza-l, 10-decane-diamine and... 

Copolymerization of two monomers with different substituents was used as another approach for depressing the transition temperatures of the polymers For example, a copolyester prepared from an equimolar mixture of cyano- and methoxyhydro-quinone and l,10-decane-h(x(p-chloroformylbenzoyloxy)decane had a melting point of 133 °C and a clearing temperature of 177 °C, while the corresponding temperatures of the cyano-substituted homopolymer were 157 and 219 °C. 

The photo-cured poly(diol-tricarballylate) (PDT) degradable bioelastomers were prepared based on the polycondensation reaction between tricarballylic acid and alkylene diols such as 1,6-hexanediol, 1,8-octanediol, 1,10-decanediol and 1,12-dodecanediol, followed by acrylation and photo-cross-linking, as shown in Scheme 8.29.The PDT prepolymers, such as poly(l,6-hexane diol-co-tricarballylate) (PHT), poly(l,8-octane diol-co-tricarballylate) (POT), poly(l,10-decane diol-co-tricarballylate) (PDET and poly(l,12-dodecane... 

Decan-l,10-diol [112-47-0] M 174.3, m 72.5-74 . Crystd from dry ethylene dichloride. 

Dodecane-l,10-dioic acid (decane-1,10-dicarboxylic acid) [693-23-2] M 230.3, m 129°, b 245°/10mm, pK ,t -4.8. Crystd from water, 75% or 95% EtOH (sol 10%), or glacial acetic acid. 

To a — 78 C solution of l,10,10-trimethyl-5-methylsulfonyl-4-(2-propenyl)-3-oxa-5-aza-4-borabicyclo-[5.2.1.02 >]decane (theoretically 10 mmol prepared as described in Section 1.3.3.3.3.1.1.4.) in 30 raL ol THK arc added 352 mg (8 mmol) of acetaldehyde. The mixture is stirred for 2 h at —78 "C and is then allowed to warm to r.t. The mixture is poured into dilute hydrochloric acid and extracted with diethyl ether. The... 

A general method for the preparation of 2-hydroxyalkyl-l,4,7-triazacyclodecane macrocycles 202, 203, 204 with a single pendant arm < 1999J(P 1)1211 > through reaction of epoxides has been achieved from the ortho amide derivative l,4,7-triazatricyclo[5.2.1.04 10]decane 40 (Scheme 30) <1999J(P1)1211>. 

Other macrocyclic ligands 218 with a single pendant arm have been prepared from l,4,7-triazacyclio[5.2.1.04 10]-decane 40 <1996ICA(246)343> by reacting with appropriate alkyl bromide/alkenyl bromide followed by base hydrolysis (Scheme 34). 

The monoammonium salt of l,4,7-triazatricyclo[5.2.1.04 10]decane 72 when treated with water led to the desired substituted 1,4,7-triazacyclononane 73 in 92% yield (Equation 30) <20010L2855>. 

Many researchers have reported the structure-thermal property correlations in LCPs from substituted hydroquinones (HQs) and dicarboxylic acids. Lenz and co-workers have investigated the liquid crystallinity of the polyarylates obtained from substituted HQs and terephthalic acid (TA) [6-10], substituted HQs and l,10-bis(phenoxy)decane-4,4/-dicarboxylic acid [8], and substituted HQs and a,oo-bis(phenoxy)alkane-4,4/-dicarboxylic acid [11], Kricherdorf and Schwarz [12] and Osman [13] reported the liquid crystallinity of the polyarylates obtained from substituted HQs and 1,4-cyclohexanedicarboxylic acid, while Krigbaum el al. [14], Heitz and co-workers [15] and Kricherdorf and Engelhardt [16] investigated the liquid crystallinity of the polyarylates synthesized from substituted HQs and substituted TAs. In addition, Jackson reported the liquid crystallinity and the moduli of fibers and injection molded specimens of the polyarylates... 

In 1984, Giibble et al. reported for the first time a novel l,10-bis-(6-methyl-5H-benzo[fc]carbazol-ll-yl)decane (469) which has potential bifunctional nucleic acid intercalating properties (406). To function as anti-tumor active drugs, one of the most important cytostatic mechanisms of action of coplanar annelated polycyclic compounds is their intercalation with DNA (405). Ten years later, Kucklander et al. studied a series of 5H-benzo[ 7]carbazole quinone derivatives for their cytotoxic activity against colon and lung cancer cells, and found that the heteroannelated 5H-benzo[ 7]carbazole quinone derivative 470 was the most active among the various analogs (407) (Scheme 4.2). 

Zu einem anderen Mechanismus s. Lit.451 weitere Beispiele s. Lit.452. 3,4-(l,10-Decandiyl)-furazan-2-oxid liefert mit 1-Tetradecen unter C, 2-Ringspaltung 1,10-Bh-[5-dodecyl-4,5-dihydro-1,2-oxazol-3-yl -decan (65 %)453 ... 

Agent l-10,l,10-Bis[(3 -dimethylcarbamoxy-a-picolinyl)ethylamino] decane dimethobromide 1/2 hydrate... 

DODECACHLOROOCTAHYDRO-1.3.4-METHENO-1H-CYCLOBUTA(c,d)PENTALENE DODECA-CHLOROPENTACYCLODECANE DODECACHLORO-PENTACYCLO(3,2,2,o2.6 o3.9,o5.10)DECANE ENT 25,719 FERRIAMICIDE HEXACHLOROCYCLOPENTADI-ENEDIMER l,2,3,4,5,5-HEXACHLORO-l,3-CYCLO-PENTADIENE DIMER HRS 1276 NCI-C06428 PERCHLORODIHOMOCUBANE PERCHLOROPENTA-CYCLODECANE PERCHLOROPENTACYCLO-(5.2,1, o2. 5,o3.5,o5.8)DECANE... 

Neoergosterol is available in a single step by treating ergosterol with dibutyl peroxide in n-decane under reflux. A 2-methoxy-4-methyloestra-1,3,5(10)-triene (161) is oxidized by peracetic acid to give the 5j5-hydroxy-l(10),3-dien-2-one... 

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