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Kohlrauschs law of independent ionic mobilities

Each ion will make a contribution to the total conductivity of the solution  [Pg.443]

Watch carefully the subscripts here, i.e. c+stoich, c stoich and Cstdch [Pg.443]

It is used for calculating the limiting molar conductivity, JsP, of an electrolyte from tabulated individual limiting ionic conductivities, X°, i.e. for very, very low concentrations. Under such conditions, the law can handle calculations of predicted limiting molar conductivities for both strong and weak electrolytes. [Pg.443]

For weak electrolytes this can be extremely useful, since it is very difficult to determine A° by extrapolation of experimental A values at various concentrations (see Sections 11.7 and [Pg.443]

There are two ways of using the law for estimating A° for a weak electrolyte, e.g. CH3COOH  [Pg.443]




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