Keywords REACTION TEMPERATURE

With its flexible and logical search language, REACCS can retrieve molecular stmctures, the atoms and bonds that are transformed ia a reaction, relative and absolute stereochemistry, the role (reactant, product, solvent, or catalyst) of a molecule ia a reaction, reaction data (eg, temperature and yield), hterature references, and keyword descriptions of reaction types. [Pg.125]

Keywords gas-solid reaction, acetone gas imbibition, inclusion compounds, desorption temperatures... [Pg.432]

Keywords 1,4-Dicarbonyls, aldehydes, niobium pentachloride (NbCls), homogeneous catalysis, solvent-free, room temperature, condensation, Knoevenagel reaction, trisubstituted alkenes... [Pg.1]

Keywords Nitroalkanes, a,p-unsaturated ketones, aldehydes, CTAOH, solvent-free, room temperature, Michael reaction, Henry reaction, p-nitroalcohols... [Pg.9]

Keywords Allyl bromides, benzyl bromides, diborylmethane derivative, Pd-catalysts such as [Pd-PEPPSI-IPr] (l)/Pd[P(f-Bu)3l2 (2), aq. KOH, dioxane, room temperature, Suzuki-Miyaura cross-coupling (SMC) reaction, C-C bond formation, regio- and chemoseletivity, homoallylboronates, alkylboronates... [Pg.12]

Keywords Aldehydes, nitromethane, chiral diamine ligand (l)-Cu(OAc)2 complex as catalyst, n-propanol, room temperature, enantioselective Henry reaction, nitroalcohols... [Pg.17]

Keywords Aldehydes, bromoniromethane, solvent-free, carbonate on silica, room temperature, Henry reaction, a-bromonitroalcohols, Amberlyst I5/AC2O, heterogeneous catalysis, dehydration, diastereoselectivity, (Z)-a-bromonitroalkenes... [Pg.21]

Keywords Anilines, quinones, f-BuONO, DMSO-H2O, diazotization, room temperature, direct C-H arylation, radical reaction, 2-aryl-l,4-benzoquinones... [Pg.24]

Keywords Arylaldemines, trimethylsilyl ketene acetal, lithium chloride, DMF, room temperature, Mukaiyama-type Mannich reaction, p-amino esters... [Pg.31]

Keywords N-Phosphinoyl benzaldimines, trimethyl(trichloromethyl)silane, tetrhydrofuran, room temperature, nucleophilic addition reaction, N-phosphinoyl-a-(trichloromethyl) benzylamines... [Pg.32]

Keywords a-Trifluoromethylated esters, vinyl ketones, XPhos (I), organocatalyst, N,N-dimethyformamide, room temperature, Michael reaction, Michael adducts... [Pg.33]

Keywords Ferrocenyl alcohol, nucleophiles, acetonitrile, room temperature, C-H activation, substitution reaction, ferrocene functionalities... [Pg.39]

Keywords Isatin, hydrazine hydrate, l,l-bis(methylthio)-2-nitroethylene, ethanol, room temperature, one-pot multicomponent reaction, spirooxindole-pyrazolines... [Pg.45]

Keywords Juglone, styrenes, DDQ, B(OAc)3, dichloromethane, room temperature, cycloaddition, Diels-Alder reaction, angucyclinones, ll-hydroxybenz[a]anthracene-7,12-diones... [Pg.56]

Keywords Indoles, istains/acenaphthaquinone, sulfamic acid, ethanol-water (1 1), room temperature, one-pot pseudo-multicomponent reaction, functionalized 3,3-f>A(indol-3-yl) indolin-2-one scaffolds / 2,2-W5(indol-3-yl)acenaphthylen-l(2/f)-one derivatives... [Pg.64]

Keywords Dienaminodioate, cinnamaldehydes, allyl amine, trifluoroacetic acid, chloroform-acetonitrile (1 1), room temperature, one-pot cascade annulation, Diels-Alder reaction, air oxidation, polyfunctional biaryl-2-carbaldehydes... [Pg.70]

Keywords Isatins, malononitrile, 2-pyrazolin-5-ones, sodium bicarbonate, grinding, room temperature, solvent-free, one-pot multicomponent reaction, heterocycles, spiropyranyl-oxindoles, spiro[indoline-3,4 (l// )-pyrano-[2,3-c]pyrazol]-2-ones... [Pg.71]

Keywords Strecker reaction, a-aminonitriles, carbonyl compounds, TMSCN, Zr0Cl2.8H20, homogeneous catalyst, one-pot synthesis, multicomponent reaction (MCR), solvent-free, room temperature... [Pg.75]

Keywords Substituted amines, amines, a,p-unsaturated alkenes, ZrOCla-SHaO/montmorillon-ite KIO, heterogeneous catalysis, solvent-free, room temperature, Mannich reaction, Michael addition... [Pg.77]

Keywords 1,3-Dicarbonyls, amines, Sc(OTf)3, reusable catalyst, solvent-free, room temperature, condensation reaction, p-enamines... [Pg.79]

Keywords Aryl iodides, aliphatic amines, CuBr, racemic-1,1 -binaphthyl-2,2 -diol (rac-BINOL), K3PO4, N,N-Dimethyl formamide (DMF), room temperature, coupling reaction, amination, N-arylation of aliphatic amines... [Pg.82]

Keywords 1-Substituted imidazoles, isothiocyanates, cyanophenylacetylene, catalyst-free, solvent-free, room temperature, multi-component reaction, N-(Z-alkenyl)imidazole-2-car-bothioamides, stereoselectivity... [Pg.83]

Keywords Carbonyl compounds, amines, thioacids, alcohol, isonitriles, room-temperature, one-pot multicompinent reaction, Ugi reaction, endothiopeptides... [Pg.88]

Keywords Amines, 1,4-dicarbonyls, montmorillonite-KSF, iodine, room temperature, Paal-Knorr reaction, condensation, substituted pyrroles... [Pg.103]

Keywords Aromatic amines, a,p-unsaturated aldehydes, acetoacetate ester, ethanol, CAN, homogeneous catalysis, room temperature, one-pot multicomponent domino synthesis, 1,4-dihydropyridines, Hanztsch reaction... [Pg.109]

Catalyst 1-ButyIimidazohum tetrafluoroborate ([Hbim][BF4] ionic liquid, reusable catalyst) Keywords o-Aminoaryl ketones, a-methylene ketones, [Hbim][BF4] (IL), methanol, room temperature, ultrasound, condensation, tandem reaction, quinolines, reusable catalyst... [Pg.110]

Keywords a-Azido esters, isocyanates, PhaP, acetonitrile, room temperature, domino reaction, multi-component reaction, /V-carbamoyl hydantoins, Staudinger reaction... [Pg.125]

Keywords Alkyl halides, alkynes, sodium azide, CU2O, methanol, room temperature, multi-component reaction, click synthesis, heterocycles, substituted 5-alkynyl 1,2,3-triazoles... [Pg.127]

Keywords Sulfonamides, vinyl ketones, toluene, DBU, room temperature, Michael addition, cascade reaction, cyclization, functionalized 3-aroyl-4-hydroxy-4-arylpiperidines, stereoselectivity... [Pg.132]

Keywords Benzoyl thiocyanate, oxalyl chloride, primary amines, dichloromethane, room temperature, multicomponent reaction, 2-thioparabanic acids... [Pg.135]

Keywords 2-Azido-3-arylacrylates, terminal alkenes, dichloromethane, palladium acetate, tri-fluoroacetic acid (TEA), oxygen-atmosphere, room temperature, domino reaction, intramolecular cyclization followed by olefination, 3-alkenyl indoles... [Pg.147]

Keywords Indoles, aromatic amines, oxetanyl aldehydes, asymmetric catalyst A, diethyl ether, room temperature, asymmetric multicomponent reaction, aza-Diels-Alder reaction, indole-alkaloid-type polycycles, diastereoseltivity... [Pg.151]

Keywords 2-Ethynylanilines, sulfonyl azide, nitroolefins, CuBr, 1,4-dioxane, room temperature, one-pot three-compOTient reaction, polysubstituted indoles... [Pg.153]

Keywords 6-Formyl-2,3-climethoxybenzoic acid, secondary amines, isocyanides, silica NPs, heterogeneous recyclable catalyst, solvent-free, room temperature, one-pot three-component reaction, l-carboxamido-3-oxoisoindolines... [Pg.155]

Keywords orf/to-Phthalaldehyde/ 3,4-dimethoxy ori/to-phthalaldehyde, amines, isonitriles, NaHS03, DMSO-H2O (1 1), room temperature, one-pot three-component reaction, 1-car-boxamido-3-oxoisoindoles... [Pg.156]

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