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Ketone reaction summary

Summary of Reactions Discussed in Earlier Chapters That Yield Aldehydes and Ketones... [Pg.710]

Summary of Reactions of Aldehydes and Ketones Discussed in Earlier Chapters... [Pg.713]

In summary, the Bucherer-Bergs reaction converts aldehydes or ketones to the corresponding hydantoins. It is often carried out by treating the carbonyl compounds with potassium cyanide and ammonium carbonate in 50% aqueous ethanol. The resulting hydantoins, often of pharmacological importance, may also serve as the intermediates for amino acid synthesis. [Pg.272]

Summary of the Relationship between Diastereoselectivity and the Transition Structure. In this section we considered simple diastereoselection in aldol reactions of ketone enolates. Numerous observations on the reactions of enolates of ketones and related compounds are consistent with the general concept of a chairlike TS.35 These reactions show a consistent E - anti Z - syn relationship. Noncyclic TSs have more variable diastereoselectivity. The prediction or interpretation of the specific ratio of syn and anti product from any given reaction requires assessment of several variables (1) What is the stereochemical composition of the enolate (2) Does the Lewis acid promote tight coordination with both the carbonyl and enolate oxygen atoms and thereby favor a cyclic TS (3) Does the TS have a chairlike conformation (4) Are there additional Lewis base coordination sites in either reactant that can lead to reaction through a chelated TS Another factor comes into play if either the aldehyde or the enolate, or both, are chiral. In that case, facial selectivity becomes an issue and this is considered in Section 2.1.5. [Pg.78]

In summary, although the computed structural details of the reaction profile depend on the method used for calculations, the general salient mechanistic conclusion is that the dioxetane thermolysis starts with the 0—0 bond rupture to generate the 0C(H2)—C(H2)0 triplet diradical, which is followed by C—C bond cleavage to afford the final ketone products one of them is formed preferentially in its triplet excited state. Since even simple 1,2-dioxetanes still present a computational challenge to resolve the controversial thermolysis mechanism, the theoretical elucidation of complex dioxetanes constitutes to date a formidable task. [Pg.1182]

Numerous experimental combinations of process conditions (SS or US), hydrogenation gas (H2 or D2), and solvent (H2O or D2O) have been explored. A summary of combinations we have chosen for study is presented in Table 2. In this table it is seen that the experiments are labeled B1-B7 for 3B20L and P1-P6 for 14PD30L. The second column lists the experimental conditions, whereas the third column lists the initial system concentration based on 100 mM of substrate and the amount of catalyst used. The penultimate column lists the final (extent of reaction > 95%) selectivity to ketone (2-butanone or 3-pentanone) and the final column lists the pseudo-first order substrate loss rate coefficient. The dataset contained in Table 2 enables numerous conclusions to be made regarding the reaction systems. The differences in initial concentrations (e.g., 67 versus 100 M/g-cat.) arise from the chosen convenience of having similar activities and therefore comparable reaction times. [Pg.219]

In summary, the direct insertion of zinc dust to organic halides is an excellent method for preparing a broad range of polyfunctional organozinc halides bearing various functional groups like an ester" , an ether, an acetate" , a ketone, cyano", halide" , N,N-bis(trimethylsilyl)amino °, primary and secondary amino, amide, phthalimide , sulfide, sulfoxide and sulfone , boronic ester , enone " or a phosphonate . An alternative method is based on transmetalation reactions. [Pg.296]

II. Functionalization of the Angular Methyl Groups / 237 General principles of substitution / 237 Lead tetraacetate oxidations / 240 Hypohalite reactions / 246 Photolysis of nitrites (Barton reaction) / 253 A-Chloroamine reactions (Hoffmann-Lofller reaction) / 257 Ketone irradiations / 260 Summary / 264... [Pg.244]

Using an excitation wavelength of X = 350 nm Choi et al. recently observed that the solid-state reaction of the c/s-ketone 7 may be carried out to completion to give the cw-photoproduct cis-8 with no loss of stereoselectivity in a remarkably clean solid-to-solid reaction. A summary of the reaction in Scheme 30 gives the melting points of the pure reactant (146°C) and product (104°C) phases and illustrates some mechanistic details. [Pg.234]

Summary Syntheses of Ketones and Aldehydes 837 18-11 Reactions of Ketones and Aldehydes Introduction to Nucleophilic Addition 839... [Pg.17]

Mechanism 18-7 Wolff-Kishner Reduction 864 Summary Reactions of Ketones and Aldehydes 865 Essential Terms 868 Study Problems 870... [Pg.18]

In studying reactions of other functional groups, we have already encountered some of the best methods for making ketones and aldehydes. Let s review and summarize these reactions, and then consider some additional synthetic methods. A summary table of syntheses of ketones and aldehydes begins on page 837. [Pg.829]


See other pages where Ketone reaction summary is mentioned: [Pg.301]    [Pg.567]    [Pg.390]    [Pg.11]    [Pg.28]    [Pg.415]    [Pg.20]    [Pg.260]    [Pg.107]    [Pg.260]    [Pg.323]    [Pg.23]    [Pg.317]    [Pg.86]    [Pg.685]    [Pg.343]    [Pg.168]    [Pg.532]    [Pg.626]    [Pg.717]    [Pg.199]    [Pg.317]    [Pg.532]    [Pg.626]    [Pg.717]    [Pg.62]   
See also in sourсe #XX -- [ Pg.630 , Pg.631 , Pg.632 , Pg.633 ]

See also in sourсe #XX -- [ Pg.630 , Pg.631 , Pg.632 , Pg.633 ]




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Reaction summary

Summary Reactions of Ketones and Aldehydes

Summary of Aldehyde and Ketone Addition Reactions

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