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Ketones and their Derivatives

The halogenation-dehydrohalogenation of ketones and their derivatives is the most widely applied method for the preparation of unsaturated ketones, and the different combinations of alternatives which exist for both steps extend the scope of this approach. Consequently, this route will be discussed in considerable detail. [Pg.267]

Although both aliphatic and aromatic ketones have been studied, the aromatic ketones are more useful in commercial practice, since their absorptions occur at longer wavelength (lower energy) and their quantum yields are higher [Ledwith, 1977 Pappas, 1988]. Ketones and their derivatives undergo homolysis by one or both (often simultaneously) of two processes a-scission and electron transfer [Padon and Scranton, 1999]. a-Scission involves... [Pg.220]

Friedel-Crafts Acylation, The Friedel-Crafts acylation procedure is the most important method for preparing aromatic ketones and their derivatives. Acetyl chloride (acetic anhydride) reacts with benzene in the presence of aluminum chloride or acid catalysts to produce acetophenone [98-86-2], CgHgO (1-phenylethanone). Benzene can also be condensed with dicarboxylic acid anhydrides to yield benzoyl derivatives of carboxylic acids. These benzoyl derivatives are often used for constructing polycyclic molecules (Haworth reaction). For example, benzene reacts with succinic anhydride in the presence of aluminum chloride to produce p-benzoylpropionic acid [2051-95-8] which is converted into a-tetralone [529-34-0] (30). [Pg.40]

ALKYLATION AND ACYLATION OF ALDEHYDES, KETONES AND THEIR DERIVATIVES... [Pg.1475]


See other pages where Ketones and their Derivatives is mentioned: [Pg.390]    [Pg.22]    [Pg.711]    [Pg.724]    [Pg.810]    [Pg.1]    [Pg.3]    [Pg.5]    [Pg.7]    [Pg.9]    [Pg.11]    [Pg.13]    [Pg.15]    [Pg.17]    [Pg.19]    [Pg.21]    [Pg.23]    [Pg.25]    [Pg.27]    [Pg.29]    [Pg.31]    [Pg.34]    [Pg.679]    [Pg.463]    [Pg.56]   


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Aldehydes, Ketones, and their Derivatives

Ketone derivatives

Ketones and derivatives

Their Derivatives

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