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Ketones aldehydes, degradation with

Ketones from aldehydes Degradation with loss of 1 C>atom... [Pg.349]

Ozone can be used to completely oxidize low concentrations of organics in aqueous streams or partially degrade compounds that are refractory or difficult to treat by other methods. Compounds that can be treated with ozone include alkanes, alcohols, ketones, aldehydes, phenols, benzene and its derivatives, and cyanide. Ozone readHy oxidizes cyanide to cyanate, however, further oxidation of the cyanate by ozone proceeds rather slowly and may require other oxidation treatment like alkaline chlorination to complete the degradation process. [Pg.163]

Determination of the residual antioxidant content in polymers by HPLC and MAE is one way to determine the amoimt needed for reasonable stabilization of a material, and also to compare different antioxidants and their individual efficiencies. During ageing and oxidation of PE, carboxyhc acids, dicarboxylic acids, alcohols, ketones, aldehydes, n-alkanes and 1-alkenes are formed [86-89]. The carboxyhc acids are formed as a result of various reactions of alkoxy or peroxy radicals [90]. The oxidation of polyolefins is generally monitored by various analytical techniques. GC-MS analysis in combination with a selective extraction method is used to determine degradation products in plastics. ETIR enables the increase in carbonyls on a polymer chain, from carboxylic acids, dicarboxyhc acids, aldehydes, and ketones, to be monitored. It is regarded as one of the most definite spectroscopic methods for the quantification and identification of oxidation in materials, and it is used to quantify the oxidation of polymers [91-95]. Mechanical testing is a way to determine properties such as strength, stiffness and strain at break of polymeric materials. [Pg.145]

Schonberg A. and Moubacher R. (1952) The Strecker degradation of a-amino acids. Chem. Rev. 50, 261-77. Schonberg A., Moubacher R. and Mostafa A. (1948) Degradation of a-amino acids to aldehydes and ketones by interaction with carbonyl compounds. J. Chem. Soc. 176-82. [Pg.381]

When the reactivity of reactant (R-CH2-X) is relatively high, the condensation reactions take place more easily than the degradation reactions. As a result, the selectivity to the condensation products becomes high. This is the case of the reaction with aldehydes or ketones. The reaction with carboxylic acids and esters is more difficult and the reaction with nitriles is the most difficult especially in view of the selectivity based on HCHO. [Pg.195]

The difficult translation of SOMO activation to cyclic ketones was achieved with the help of catalyst 6, which was developed earUer for Diels-Alder reactions of cyclic ketones via iminium activation. The difficulty Hes in the fact that aldehydes and ketones exhibit largely different steric and electronic properties with respect to catalyst interactions [16]. Competitive catalyst degradation under the oxidative conditions (i.e., oxidation of the methyl group attached to furan) was circumvented by transforming the methyl into a trifluoromethyl group, or by direct replacement of the furyl ring with less electron-rich heteroaryl systems such as benzofuran (8) or benzothiophene (9), which are less sensitive to oxidation (Scheme 39.5). [Pg.1172]

Aldehydes and ketones form derivatives with 2,4-dinitrophenylhydrazine. These derivatives develop a red color upon treatment with alkali. Although the intensity of the color is somewhat dependent upon the type of aldehyde compound, reaction temperature, and time allowed for color development, the method is generally suitable for assessing degradation... [Pg.81]

The reaction of carboxylic acids, aldehydes or ketones with hydrazoic acid in the presence of a strong acid is known as the Schmidt reaction A common application is the conversion of a carboxylic acid 1 into an amine 2 with concomitant chain degradation by one carbon atom. The reaction of hydrazoic acid with a ketone 3 does not lead to chain degradation, but rather to formation of an amide 4 by formal insertion of an NH-group. [Pg.251]

Much of the chemistry of monosaccharides is the familiar chemistry of alcohols and aldehydes/ketones. Thus, the hydroxyl groups of carbohydrates form esters and ethers. The carbonyl group of a monosaccharide can be reduced with NaBH4 to form an alditol, oxidized with aqueous Br2 to form an aldonic acid, oxidized with HNO3 to form an aldaric acid, oxidized enzymatically to form a uronic acid, or treated with an alcohol in the presence of acid to form a glycoside. Monosaccharides can also be chain-lengthened by the multistep Kiliani-Fischer synthesis and can be chain-shortened by the Wohl degradation. [Pg.1007]

A bacterial isolate APN has been shown to convert a-aminopropionitril enantioselectively to L-alanine (94% yield, 75% e e). However, the major disadvantage of this approach, is the low stability of most aminonitriles in water (for example a-aminophenylacetonitrile in water of pH 7, degrades completely within 48 hours). The aminonitriles are always in equilibrium with the aldehyde or ketone and ammonia/HCN. Polymerisation of hydrogen cyanide gives an equilibrium shift resulting in the loss of the aminonitrile. Therefore, a low yield in amino adds is to be expected, which makes this method less attractive for the industrial synthesis of optically active amino adds. [Pg.280]


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Aldehydes with ketones

Degradation ketones

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