Iron naphthalocyanine

Coowar, R, O. Contamin, M. Savy, and G. Scarbeck (1998). Electrocatalysis of O2 reduction to water in different acid media by iron naphthalocyanines. J. Electroanal. Chem. 246, 119-138. 

Even though most authors agree that the M(ll) state is the active site for O2 reduction [15, 20, 65-67, 70, 72, 88, 89, 97-99, 102, 105, 123, 124] for FePc (iron phthalocyanine) andFeNPc (iron naphthalocyanine) [125-127], it has been proposed... 

Biloul A, Coowar F, Contamin O, Scarbeck G, Savy M, Van den Ham D, Riga J, Verbist JJ (1990) Oxygen reduction in acid media on supported iron naphthalocyanine - effect of isomer configuration and pyrolysis. J Electroanal Chem 289 189-201... 

Biloul, A., Coowar, R, Contamin, O., et al. (1990). Oxygen Reduction in Acid Media on Supported Iron Naphthalocyanine Effect of Isomer Configuration and Pyrolysis, J. Electroanal. Chem., 289, pp. 189-201. 

Iron(ll) 2,11,20,29-Tetra(to7-buty I)-1,2-naphthalocyanine "typical Procedure 7 1... 

Bis(ftTf-butyIisocyano)iron(II) 2,5,ll,14,20,23,29,32-Octaheptyl-2,3-naphthalocyanine (33) Typical Procedure 281... 

Isocyanides may be coordinated to the central iron or ruthenium atom in the corresponding 2,3-naphthalocyanines, e.g. 7. 

Bis(l,4-diisocyanobenzene)iron(II) 2,3-Naphthalocyanine (7, R = 4-CNC6H4) Typical Procedure 452... 

Figure 17.5 Skeleton structures of (a) polypyrrolic photosensitizers (i) porphyrin, (ii) chlorine, (Hi) bacteriochlorin, (iv) phthalocyanine, (v) naphthalocyanine, (vi) texaphyrin (b) examples of metalloderivatives (c) photosensitizers incorporating the metallodrug moieties (x-xii) cisplatin- and/or carboplatin-like structures, (xiii) iron sulphur nilrosy cluster...

Hitmen, C., F. Coowar, and M. Savy (1989). Oxygen reduction in acid media Investigations by electroreflectance on adsorbed iron phthalocyanine and naphthalocyanine layers. J. Electroanal. Chem. 264,167-180. 

Magner, G., M. Savy, G. Scarbeck, J. Riga, and J.J. Verbist (1981). Effects of substitution of iron by molybden in the naphthalocyanine structures upon their electrocatalytic properties for O2 reduction and evolution in afkaUne media. J. Electmchem. Soc., 128, 1674—1680. 

For the first time 2,3-naphthalocyanine (2,3-Nc) is used as the macrocycle. 2,3-Naphthalocyaninato iron can be prepared by the drop-wise addition of FeCCO) to a solution of 2,3-dicyanonaphthalene in 1-chloronaphthalene at 250°C in the absence of oxygene. 

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