Iron III acetate

CIHORINE OXYGEN ACIDS AND SALTS - DICIHORDIE MONOXIDE, HYPOCIHOROUS ACID, AND HYPOCIHORITES] (Vol 5) Basic iron(III) acetate [10450-55-2]... 

Iron(III) acetate [1834-30-6], Ee(C2H202)3, is prepared industrially by treatment of scrap iron with acetic acid followed by air oxidation. Iron(III) acetate is used as a catalyst in organic oxidation reactions, as a mordant, and as a starting material for the preparation of other iron-containing compounds. 

Polymer and precursors (FeCl3, iron(III) acetate, titanium isopropoxide, silicon tetraethoxide, and copper(II) chloride) dissolved in organic solvent (acetone, ethyl acetate) and cast onto microscopic slides precursors in situ hydrolyzed... 

If the solution is diluted and boiled, a reddish-brown precipitate of basic iron(III) acetate is formed ... 

Basic iron(III) formate and basic iron(III) acetate. Separate by procedure B. 

Phosphates. There are several methods for the removal of phosphate ions. Of these, three methods will be outlined here. The first one, the zirconium nitrate method is by far the most convenient if correctly performed, all phosphate ions are quantitatively and rapidly removed as the highly insoluble zirconium phosphate. The iron(III)-acetate method has been quite extensively used in the past it can be adapted if zirconium nitrate is not available in the laboratory its theoretical background is quite interesting too. Finally, the tin(IV) chloride method is also described because this method can be applied in the presence of the rarer elements (cf. Section VII.23). 

Oxygenation of ligands has also been observed. An a-diimine iron(II) complex has been effectively hydroxylated as a result of oxidation by cerixim(IV) (equation 63). Aerial oxidation in dimethylformamide of an iron(III) acetate complex results in the conversion of an ethano linkage to dioxo (equation 64). During the formation of the related nickel(II) complex (64), the modified complex (65) was isolated. It is likely that the product arose by reaction of 1,2-diaminoethane... 

Iron (III) chloride solution deep-red colouration, owing to the formation of a complex ion, [Fe3(OH)2(CH3COO)6] . On boiling the red solution it decomposes and a brownish-red precipitate of basic iron(III) acetate is formed ... 

Fe compounds iron(III) sulfate, iron(III) hydroxide, iron(III) arsenate, iron(III) acetate, iron(III) chromate. 

Traces of copper or iron scarcely influence the photo-oxidative stability of PPE. However, if PPE containing copper or iron compounds is mixed with impact modified polystyrene (SB), the result is a significant reduction in photo-oxidative stability. Iron(III)chloride causes strong degradation, followed by copper(II)chloride and acetate the least damaging is iron(III)acetate [86]. 

---