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Iron complex compounds, anions with pyridine

My co-worker J. Sedlmeier then held the view that the amine-containing iron carbonyl complexes were also ionic compounds (VII, 14, 21). Hence the compound Fe2(CO)4(en)3 (en= 1,2-ethylenediamine) was formulated as [Fe(en)3]2+[Fe(CO)4]2. Systematic investigations revealed that reactions of the iron carbonyls with other nitrogen and oxygen donors likewise involved valency disproportionation of the metal with concomitant formation of mono- and polynuclear carbonylferrates, viz., [Fe(CO)4]2, [Fe2(CO)8]2-, [Fe3(CO)n]2-. R. Werner (VII, 15, 17, 19, 20) even discovered and characterized compounds containing the tetranuclear anion [Fe4(CO)13]2, the first being that from pyridine and iron carbonyl, viz.,... [Pg.4]


See other pages where Iron complex compounds, anions with pyridine is mentioned: [Pg.126]    [Pg.2186]    [Pg.2185]    [Pg.98]    [Pg.190]    [Pg.193]    [Pg.279]    [Pg.495]    [Pg.89]    [Pg.291]    [Pg.127]    [Pg.196]    [Pg.218]    [Pg.101]   
See also in sourсe #XX -- [ Pg.184 ]

See also in sourсe #XX -- [ Pg.184 ]




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Anion complexation

Anion, , complex

Complex anionic

Complexes pyridine

Complexes with iron compounds

Compounds anionic

Iron complex anion

Iron complex compounds

Iron complex compounds, anions

Iron complexes anionic

Iron complexes pyridine

Iron complexes, with

Iron compounds

Pyridine compounds

Pyridine with

Pyridines complexation

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