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Introduction of Characteristic Numbers

A chemical process is a combination of a chemical substance transition and a technical apparatus. The main factors which are influenced by thermodynamics, kinetics and design properties of the apparatus can be combined in three characteristic numbers. These are  [Pg.84]

ATad provides direct information on the exothermic effect of the chemical reaction. Therefore it is of special importance for the safety assessment of chemical processes. Typical values range from 10 K for either highly diluted syntheses or for reactions with a very small exothermicity, up to 400 K for highly concentrated or strongly exothermic reactions. Decompositions may even have significantly higher values. [Pg.84]

The Damkoehler number Da represents the ratio of a characteristic reaction time to the kinetic time constant of the reaction and is therefore a measure for the reaction time. The attribute characteristic refers to the individual definition necessary for each [Pg.84]

The third characteristic number, which was first introduced by Westerterp as a modified Stanton number, combines all relevant parameters which determine the cooling capacity of a chemical reactor. This characteristic number is equivalent to the time constant of cooling in the dimension bearing domain [Pg.85]

This group of characteristic numbers is supplemented by the so-called thermal reaction number [Pg.85]


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