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Interferogram centerburst

Figure 3. Signal at the detector from a polychromatic source. This interferogram shows the form of the signal about a DC offset. Note the sharp "centerburst" at 5 = 0, the only point where all of the frequencies interfere constructively. This feature is the reason gain ranging is necessary in FT absorption spectroscopy. Figure 3. Signal at the detector from a polychromatic source. This interferogram shows the form of the signal about a DC offset. Note the sharp "centerburst" at 5 = 0, the only point where all of the frequencies interfere constructively. This feature is the reason gain ranging is necessary in FT absorption spectroscopy.
Phase correction in contrast to the theoretical expectation, the measured interferogram is typically not symmetric about the centerburst (.v = 0). This is a consequence of experimental errors, e.g., frequency-dependent optical and electronic phase delays. One remedy is to measure a small part of the interferogram doublesided. Since the phase is a weak function of the wavenumber, one can easily interpolate the low resolution phase function and use the result later for phase correction. If there is considerable background absorption, phase errors may falsify the intensities of bands in the difference spectra. To avoid such phase errors for difference spectroscopy, the background absorbance should therefore be less than one. [Pg.621]

The interferogram of a polychromatic source exhibits a maximum at <5 = 0, which is called a centerburst (Fig. 2b). At zero retardation both parts of the beam have equal optical path and consequently neither constructive nor destructive interference is produced all frequencies pass the beam splitter undisturbed and the intensity reaches a maximum. [Pg.128]

Figure 9.18. Raw interferograin (A) obtained with 1024-pixel CCD u.sing MCFT. Sample is naphthalene illuminated by 135 mW of 830 nm light, 5-sec integration B is the same data after removal of low-frequency components and zero filling to 2000 points C is after reflection of the right half of the interferogram through the centerburst. (Adapted from Reference 22 with permission.)... Figure 9.18. Raw interferograin (A) obtained with 1024-pixel CCD u.sing MCFT. Sample is naphthalene illuminated by 135 mW of 830 nm light, 5-sec integration B is the same data after removal of low-frequency components and zero filling to 2000 points C is after reflection of the right half of the interferogram through the centerburst. (Adapted from Reference 22 with permission.)...
A typical interferogram is shown in Figure 16.26. The tall part of the signal corresponds to when the two mirrors are equidistant from the beam splitter, when destructive interference between the two beams is zero, and is called the centerburst. The intensity drops off rapidly away from this, due to destructive interference. This is converted, using a computer, into the frequency domain via a mathematical operation known as a Fourier transformation (hence the name Fourier transform infrared spectrometer). A conventional appearing infrared spectrum results. [Pg.500]

Figure 1.19 The terahertz electric field 4-mm thick silicon sample (centerburst of recorded as a function of time for the back- interferogram to the right).(Reproduced with ground(centerburst of interferogram to the permission from Ref. [78]. Copyright 2004, left) and when the beam passes through a John Wiley and Sons, Ltd.)... Figure 1.19 The terahertz electric field 4-mm thick silicon sample (centerburst of recorded as a function of time for the back- interferogram to the right).(Reproduced with ground(centerburst of interferogram to the permission from Ref. [78]. Copyright 2004, left) and when the beam passes through a John Wiley and Sons, Ltd.)...
Figure 2.12. Typical interferogram of a blackbody-type source in the region of the centerburst measured by a rapid-scanning interferometer. The slight asymmetry indicates a very small amount of chirping. Figure 2.12. Typical interferogram of a blackbody-type source in the region of the centerburst measured by a rapid-scanning interferometer. The slight asymmetry indicates a very small amount of chirping.
If a double-sided interferogram has been collected and the centerburst is near the middle of the interferogram, the summation in Eq. 4.5 may be replaced by the summation... [Pg.77]


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