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Integral transformation frequency dependence

In general, the Fourier transform of the xc kernel defined by Eq. (321) is frequency dependent (even in the TD x-only case), a feature which is not accounted for by the present approximation (325). However, for the special case of a two-electron system treated within TD x-only theory, Eqs. (323) and (325) are the exact solutions of the respective integral equations. [Pg.142]

The description of imaging experiments in reciprocal space is not restricted to k space, the Fourier conjugate space of physical space. The modification of the spin density by other parameters like resonance frequencies, coupling constants, relaxation times, etc., can be treated in a similar fashion [Miil4]. For the frequency-dependent spin density, the Fourier transformation with respect to 2 is already explicitly included in (5.4.7). Introduction of a Ti-dependent density would require the inclusion of another integration over T2 in (5.4.7) and lead to a Laplace transformation (cf. Section 4.4.1). [Pg.177]

Dielectric measurements on poly(vinyl acetate) were obtained utilizing a Fourier transform dielectric spectrometer developed in our laboratory (6). A voltage step pulse was applied to the sample and the time dependent Integrated current response, Q(t), was collected by computer. The frequency dependent dielectric properties, e and e" were then obtained from the Fourier trans-... [Pg.455]

Since the integral is over time t, the resulting transform no longer depends on t, but instead is a function of the variable s which is introduced in the operand. Hence, the Laplace transform maps the function X(f) from the time domain into the s-domain. For this reason we will use the symbol when referring to Lap X t). To some extent, the variable s can be compared with the one which appears in the Fourier transform of periodic functions of time t (Section 40.3). While the Fourier domain can be associated with frequency, there is no obvious physical analogy for the Laplace domain. The Laplace transform plays an important role in the study of linear systems that often arise in mechanical, electrical and chemical kinetic systems. In particular, their interest lies in the transformation of linear differential equations with respect to time t into equations that only involve simple functions of s, such as polynomials, rational functions, etc. The latter are solved easily and the results can be transformed back to the original time domain. [Pg.478]

They would become the stars of Prigoginian statistical mechanics. Their importance lies in the fact that, whenever it is possible to determine these variables by a canonical transformation of the initial phase space variables, one obtains a description with the following properties. The action variables / ( = 1,2,..., N, where N is the number of degrees of freedom of the system) are invariants of motion, whereas the angles a increase linearly in time, with frequencies generally action-dependent. The integration of the equations... [Pg.29]

What has been presented here underscores the fact that the elastic scattering is the Fourier transform of the time-independent component of the intermediate scattering function. Naturally, the Fourier transform of a constant function produces a 5-function at > = 0, which is the elastic scattering, but this is not the same as the zero frequency component of the scattered intensity. If the time correlation function has a component that exhibits some time decay or relaxation, then the integral of the time dependant part of... [Pg.6146]

Differential equation (15.48) can be transformed into an integral equation for the scattered field, using the 1-D Green s function g (z z oj) for the 1-D Helmholtz equation, which is dependent on the position of the source z, the observation point z, and the frequency ur. This function satisfies the 1-D Helmholtz equation... [Pg.477]

The binding curves (/Vs. tdependencies) were usually transformed to obtain df/dtvs. /plots that subsequently provide kinetic constants from Eq. 2 using linear regression (11). A more elegant and precise method is integration of Eq. 2 and then introduction of substitutions / and kobs (12). The dependence of the resonance frequency/on time t can be fitted to the kinetic equation similarly as described for the optical biosensor system (13) ... [Pg.46]


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See also in sourсe #XX -- [ Pg.264 ]




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