Inorganic peroxo acids

Several acidic oxides such as M0O3, WO3 and compounds of selenium, arsenic and boron are effective catalysts for the epoxidation of alkenes by H2O2 through generation of inorganic peroxo acids, such as peroxoselenic and peroxoarsonic acids. ... 

There are a great variety of inorganic peroxo compounds where —O— is replaced by —O—O— groups. Some of these are discussed elsewhere in this book. Typical are peroxo anions such as peroxo sulfates (14-IX) and (14-X). All peroxo acids yield H2Oz on hydrolysis. Peroxodisulfate, as the... 

Inorganic and organic peroxo compounds, e.g., peroxodisulfates, peroxides, hydroperoxides, peresters Protic acids Proton acceptors Organometallic compounds... 

Gne of the most interesting simple inorganic compounds reported in recent years is peroxodisulfuryl difluoride, F—SO2—02—S02—F (mp, —55° C bp, 67° C). This is both a peroxo compound and an acid fluoride but prepared by the fiuorination of sulfur trioxide. The compound can be... 

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