Iodine compounds inorganic

Morgan, K. J. Some Reactions of Inorganic Iodine Compounds, Quarterly Reviews, VIII, 123 (1954). 

Habersbergerova, A. Radiolysis of inorganic iodine compounds in aerated borate spray solution. Radiat. Phys. Chem. 19, 403-407 (1982)... 

The rates of some redox reactions of iodine species at room temperature are given below. A discussion of the mechanisms of some reactions of Inorganic Iodine compounds may be found elsewhere. (31)... 

Salto, N. and Anbe, F. The Oxidation State of I Arising from the (n,2n) Reaction In Inorganic Iodine Compounds. Bull. Chem. Soc. Jap. 

The organic iodine compounds have lower heats of formation and greater reactivities than their chloro and bromo analogues. As ia the case of the inorganic iodides, their iadexes of refraction and specific gravities are higher than the corresponding chloro and bromo derivatives (121). 

The molecules in crystalline chlorine, bromine and iodine are packed in a different manner, as shown in Fig. 11.1. The rather different distances between atoms of adjacent molecules are remarkable. If we take the van der Waals distance, such as observed in organic and inorganic molecular compounds, as reference, then some of the intermolecular contacts in the b-c plane are shorter, whereas they are longer to the molecules of the next plane. We thus observe a certain degree of association of the halogen molecules within the b-c plane (dotted in Fig. 11.1, top left). This association increases from chlorine to iodine. The weaker attractive forces between the planes show up in the plate-like habit of the crystals and in their easy cleavage parallel to the layers. Similar association tendencies are also observed for the heavier elements of the fifth and sixth main groups. 

See other inorganic acids, oxidants, oxohalogen acids, iodine compounds... 

See Other INORGANIC ACIDS, OXIDANTS, OXOHALOGEN ACIDS, IODINE COMPOUNDS... 

Chemical oxidation of silyl enolates has been performed with a variety of inorganic and organic oxidants such as ozone, copper(II) salts, Pb(OAc)4, Ag20, hypervalent iodine compounds such as iodosobenzene in methanol, (NH4)2[Ce(N03)6], xenon difluoride, tetranitromethane, halogens, nitronium-, diazonium- and triphenylmethyl salts, chloranil and ddq. 

However, we believe that the inorganic species predominate because they react instantaneously with sulfite (56), whereas organic iodine compounds have significant reaction times (57). We did not add sulfurous acid, which converts IOs to T. On the basis of this data, we suggest that oxidation of I to I03 in the marine atmosphere may be more important than the corresponding reaction in seawater for the recycling of L to I03. Our data support the earlier radiochemical work of Luten et al. (53), who found similar results. 

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