Inorganic chemistry lanthanides

Herrmann, W.A. Synthetic Methods of Organometallic and Inorganic Chemistry. Lanthanides and Actinides, Thieme Medical Publishers, New York, NY,... 

T. Moeller, The lanthanides. Chap. 44, pp. 1-101, in Comprehensive Inorganic Chemistry, Vol. 4, Pergamon Press, Oxford, 1973 Lanthanides and actinides, Vol. 7, MTP International Review of Science, Inorganic Chemistry (Series Two) (K. W. Bagnall, ed.), Butterworths, London, 1975, 329 pp. 

Wietzke, R., Mazzanti, M., Latour, J.M., Pecaut, J., Cordier, P.Y., Madic, C. 1998. Lanthanide(III) complexes of tripodal N-donor ligands Structural models for the species involved in solvent extraction of actinides(III). Inorganic Chemistry 37(26) 6690-6697. 

Miguirditchian, M., Guillaneux, D., Guillaumont, D., Moisy, P., Madic, C., Jensen, M., Nash, K.L. 2005. Thermodynamic study of the complexation of trivalent actinide and lanthanide cations by ADPTZ, a tridentate N-donor ligand. Inorganic Chemistry 44(5) 1404-1412. 

Within solution inorganic chemistry, there would be no apparent reason to obtain NMR spectra at high pressures in structural characterization studies. It prevails that most applications of hp NMR spectroscopy relate to solvent exchange reactions on solvated metal ions their mechanisms often have direct bearing upon the kinetics and mechanisms of substitution of one or more solvent molecules from a metal center by other ligands. The first part of the results section provides ample illustration of the value of high-pressure measurements on transition metal and lanthanide ions, fully... 

Kohn RD, Kociok-Kohn G, Schumann H (1994) Scandium, yttrium and the lanthanides organometallic chemistry. In King RB (ed) Encyclopedia of inorganic chemistry. Wiley, New York... 

With almost all of the conceivable coordination chemistry of the expanded porphyrins still left to be explored, it cannot be over-stres that the potential for new chemistry is enormous. This is i rticularly true when account is made of the fact that the chemistry of the metalloporphyrins has played a dominant role in modern inorganic chemistry. What with the possibility to enhance the stability of imusual coordination geometries (and, perhaps oxidations states) and the ability to form stable coordination complexes with a variety of unusual cations including those of the lanthanide and actinide series, the potential for new inorganic and organometallic discoveries are almost unlimited. For instance, as with the porphyrins, one may envision linear arrays of stacked expanded porphyrin macrocycles which may have unique conducting properties and/or which could display beneficial super- or semiconducting capabilities. Here, of course, the ability to coordinate not only to cations but also to anions could prove to be of tremendous utility. 

Useful sources of information on these elements and their componnds inclnde the Gmelin Handbook / with extensive np-to-date coverage, and regular comprehensive reviews in the Handbook on the Physics and Chemistry of the Rare Earths / General acconnts of the elements, their inorganic chemistry, and coordination chemistry exist, the latter being the most np-to-date. There are also recent monographs, and compilations of in-depth and informed articles on different aspects of lanthanide chemistry and spectroscopy. ... 

Based in part on the article Scandium, Yttrium the Lanthanides Organometallic Chemistry by R. D. Kohn, G. Kociok-Kohn, H. Schumann which appeared in the Encyclopedia of Inorganic Chemistry, First Edition. 

Datta, S., Baskar, V., Li, H., and Roesky, P.W. (2007) Synthesis and structural characterization of tetra- and pentanuclear lanthanide hydroxido clusters. European Journal of Inorganic Chemistry, 26, 4216-4220. 

Shavaleev, N.M., Scopelliti, R., Gumy, R, andBunzli, J.C.G. (2008) Visible-light excitation of infrared lanthanide luminescence via intra-ligand charge-transfer state in 1,3-diketonates containing push-pull chromophores. European Journal of Inorganic Chemistry, (9), 1523-1529. 

Figure 3.9 Structures of (a) [CeL3(phen)]2 (HL = acetic acid) and (b) [EnL3(phen)]2 (HL = 2-furancarboxylic acid) [RE, black (large balls) O, grey N, black (small balls) C, white H, omitted]. (Redrawn from the CIF files of A. Panagiotopoulos et al., Molecular structure and magnetic properties of acetato-bridged lanthanide(III) dimers, Inorganic Chemistry, 34, 4918 920, 1995 [37] and X. Li et al., Synthesis, structure and luminescence property of the ternary and quaternary europium complexes with furoic acid, Journal of Molecular Structure, 604, 65-71, 2002 [48].)...

Figure 3.15 The structure of [Tb(btc)(DMF)2] nH20. (a) Each Tb center is connected to six other Tb centers through four ligands, (b) The 13.5 x 7.6 rectangle channels viewed down the c direction (Tb, black O, grey C, white H, omitted DMF and H2O guest molecules in (b) have been removed for clarity). (Redrawn from the CIF file of Z. Li et al., Synthesis, structure, and luminescent and magnetic properties of novel lanthanide metal-organic frameworks with zeolite-like topology, Inorganic Chemistry, 46 (13), 5174-5178, 2007 [74].)...

Lam, A.W.-H., Wong, W.T., Gao, S., Wen, G, and Zhang, X.-X. (2003) Synthesis, crystal structure, and photophysical and magnetic properties of dimeric and polymeric lanthanide complexes with benzoic acid and its derivatives. European Journal of Inorganic Chemistry, 149-163. 

Panagiotopoulos, A., Zafiropoulos, T.F., Perlepes, S.P., Bakalbassis, E., Masson-Ramade, 1., Kahn, O. etcd. (1995) Molecular structure and magnehc properties of acetato-bridged lanthanide(lll) dimers. Inorganic Chemistry, 34, 4918-4920. 

Li, Z., Zhu, G, Guo, X., Zhao, X., Jin, Z., and Qiu, S. (2007) Synthesis, structure, and luminescent and magnetic properties of novel lanthanide metal-organic frameworks with zeolite-like topology. Inorganic Chemistry, 46(13), 5174-5178. 

Wu, A.-Q., Guo, G.-H., Yang, C., Zheng, F.-K., Liu, X., Guo, G-C. et al. (2005) Extended structures and magnetic properties of lanthanide-copper complexes with picolinic acids as bridging ligands. European Journal of Inorganic Chemistry, (10), 1947-1954. 

Liang, Y, Hong, M., Su, W., Cao, R., and Zhang, W. (2001) Preparations, structures, and magnetic properties of a series of novel copper(II)-lanthanide(III) coordination polymers via hydrothermal reaction. Inorganic Chemistry, 40, 4574-4582. 

Desreux, J.F. (1980) Nuclear magnetic resonance spectroscopy of lanthanide complexes with a tetraacetic tetraaza macrocycle. Unusual conformation properties. Inorganic Chemistry, 19 (5), 1319—1324. 

Tse, P.K. and Powell, J.E. (1985) Study of stmctural influence on the formation constants of lanthanide-polyamino polycarboxylate complexes. Inorganic Chemistry, 24 (18), 2727-2730. 

Figure 4.2 Structure of [La(l)4Cp3S03] + [3]. (Reproduced with permission from H. Paul, P.H. Smith and K.N. Raymond, A lanthanide-amine template synthesis. Preparation and molecular structures of Ln(L)(CH3CN)(Cp3S03)3 [L= l,9-bis(2-aminoethyl)-l,4,6,9,12,14-hexaazacyclohexadecane Ln = La, Yb] and La(en)4(CH3CN)(Cp3S03)3, Inorganic Chemistry, 24, 3469, 1985. 1985 American Chemical Society.)...

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