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Ingold-Fischer persistent radical effect

The synthesis of mixed peroxides formed from /-butyl hydroperoxide and carbon-centred radicals has been studied. The reactions were strongly effected by solvents as well as catalytic amounts of Cun/Fem. The kinetic data suggest that the conditions for the Ingold-Fischer persistent radical effect are fulfilled in these cases.191 The use of Cu /Cu" redox couples in mediating living radical polymerization continues to be of interest. The kinetics of atom-transfer radical polymerization (ATRP) of styrene with CuBr and bipyridine have been investigated. The polymer reactions were found to be first order with respect to monomer, initiator and CuBr concentration, with the optimum CuBr Bipy ratio found to be 2 1.192 In related work using CuBr-A-pentyl-2-... [Pg.126]

See other pages where Ingold-Fischer persistent radical effect is mentioned: [Pg.26]    [Pg.126]    [Pg.26]    [Pg.26]    [Pg.126]    [Pg.26]    [Pg.106]    [Pg.108]   
See also in sourсe #XX -- [ Pg.126 ]

See also in sourсe #XX -- [ Pg.126 ]

See also in sourсe #XX -- [ Pg.126 ]

See also in sourсe #XX -- [ Pg.97 , Pg.126 ]



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Fischer-Ingold effect

Ingold

Ingold-Fischer persistent radical

Persistent radical effect

Persistent radicals

Radical effective

Radicals effects

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