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Inert metal complexes induced lability

Leaving Groups on Inert Metal Complexes with Inherent or Induced Lability Geoffrey A. Lawrance... [Pg.419]

LEAVING GROUPS ON INERT METAL COMPLEXES WITH INHERENT OR INDUCED LABILITY... [Pg.145]

The counterion is quite important to the outcome of this reaction. Ion pairs, which form between alkali metal ions and the complex, induce CO lability which aids in the substitution process.1 1 Large charge-delocalized cations such as PPM are much less effective in forming ion pairs. The sulislilution process shown in Eq. 15.95 occurs readily when the counterion is Na but foils when it is PPN. Another good example of this effect can be seen by comparing NaICo CO)J and PPN [ Co[Pg.356]

See other pages where Inert metal complexes induced lability is mentioned: [Pg.13]    [Pg.384]    [Pg.356]    [Pg.200]    [Pg.301]    [Pg.58]    [Pg.65]    [Pg.107]   


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