Inductively coupled plasma atomic emission spectroelectrochemistry

8 Inductively Coupled Plasma Atomic Emission Spectroelectrochemistry 

Fundamentals. The composition of liquids with respect to both identity and concentration of dissolved species can be determined with inductively coupled plasma atomic emission spectrometry (ICP-AES) [972]. The employed spectrometer can be coupled directly with an electrochemical cell wherein processes like corrosion or anodic dissolution occur. Continuous aspiration of very small liquid volumes transferred into the spectrometer allows determination of rates of dissolution as a function of various experimental parameters like electrode potential [973]. 

Instrumentation. An electrochemical flow cell (flow rate approx. 2-3 mL-min ) is connected to an electrolyte solution reservoir. The solution is supplied via a peristaltic pump. The outlet is connected to the ICP-AES. Depending on the type and 

---

See also in sourсe #XX -- [ ]

---