Induced controlled dispersion measurements

The preceding equation shows that the transit time dispersion under weak field conditions is controlled by conventional diffusion, whereas at strong fields, the main contribution to Ate arises from the field-assisted diffusion term. A crossover from Atj to Atj occurs in the field dependence of the transit time dispersion that corresponds to the crossover from Atj E to Atj E in the dependence of the transit time dispersion on the transit time. It is worth noting that all parameters describing the contribution of the preceding equation are defined by independent measurements, while the contribution of the field-induced diffusion depends on the value of the effective release time, which is poorly known and can be very different in different disordered materials. 

To understand the reasons for different predictions of different methods, Li et al. [83] measured the adhesion between a variety of polymers with well-controlled backbone chemistry These polymers include poly (4-methyl 1-pentene) [TPX], poly(vinyl cyclohexane) [PVCH], polystyrene [PS], poly(methyl methacrylate) [PMMA], and poly(2-vinyl pyridine) [PVP], poly(4-tert-butyl styrene) [PtBS], poly(acrylonitrile) [PAN], poly(p-phenyl styrene) [PPPS], poly(vinyl benzyl chloride) [PVCB]. It may be noted that, among the polymers listed above, TPX and PVCH are purely dispersive in nature. PS is predominantly dispersive with some dipole-induced dipole interactions. 

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