Indium interatomic distance

Group 13 Metals - Aluminum, Gallium, Indium, Thallium 133 Table 3.7. Interatomic distances in gallium-arsenic supermolecules. 

This class can be illustrated by the dimers [(Bu CH2)2lnSCH2Bu ]2 (In-S 2.618 and 2.623 A), [(Bu CH2)2lnSeCH2But]2 (In-Se 2.705 and 2.719 A) [215], [(Me3CCH2)2lnSePh]2, and polymeric [Me(PhSe)In(//-SePh)] j [285]. The compounds have been reviewed [113]. Some interatomic distances for other indium-sulfur and indium-selenium supermolecules are collected in Table 3.8. 

Table 3.8. Interatomic distances in indium-sulfur supermolecules.

Supramolecular self-organization, with different amounts of complexity based upon dative bonds (see Section 3.2.3.1) and secondary bonds, is observed for organoindium halides. Long indium-halogen interatomic distances (although shorter than the expected van der Waals distance (ca. 3.8 A for In- -Cl)) are observed for most structurally characterized organoindium halides. 

Fig. 94. Cutouts of Rhlujc, Pdluj, and Ptinjc (x = 3-9) units in various binary and ternary indides. The rhodium, palladium, and platinum atoms are drawn as blaek eircles, the indium atoms as open eircles. Relevant interatomic distances in pm and atom labels are indicated. The site symmetries are given in parentheses. Note, that the alkaline earth and rare earth metal atoms are omitted for clarity.

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