INDEX carbonyl complexes

Borete, calculations, 56, 361, 362 Borins, calculations, 56, 359 Borin, Julg A index, 56, 339 Borin, 1-carbonyl complex, calculations, 56, 362... 

This index is provided so that the reader might locate information about a particular complex of interest. It is organized as follows The first section contains the neutral binary complexes, followed by charged dimers, and then by larger complexes in the last section. Within each section, the complexes are ordered by the type of molecules contained. The order is as follows XH, YH2, ZH3, carbonyl, carboxyl, imine, amide, nitrile, alkyne, alkene, alkane, others. (X refers to any halogen F, Cl, Br, I Y to O, S, etc. and Z to N, P, etc.) Any alkylated or similar substitutions follow immediately after their parent group. 

Polyethylene and polypropylene blended with iron carboxylate complexes, for example, acetylacetonate (FeAcAc) and stearates (FeSt), and irradiated by UV light under accelerated aging conditions were shown to act as effective phtoactivators giving rise to rapid photoxidation as shown from the rapid rate of carbonyl formation without any induction period (see Fig. 16.4a for FeAcAc in HDPE) and with a reduction in molar mass (see Fig. 16.2a for FeSt in LDPE). However, these complexes have been shown to cause considerable oxidation to both PE and PP during processing reflected in a sharp increase in the polymer s melt flow index (reflecting chain scission and drop in molar mass) (Fig 16.4b) and act, therefore, as thermal prooxidants and cannot be used without the use of additional antioxidants in the system [2,3,17-19,48,49]. 

Martinez et al. (1996) observed a linear inverse relationship between protein carbonyl content and complex IV/complex I ration (which was used as an index of imbalance between mitochondrial respiratory complexes) in synaptic mitochondria in five age groups of female OF-1 mice (r = -0.99, P <0.001). 

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