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Indan ring

The MS-MS data from metabolite 5 shows a base peak at m/z 437, at an increase of 16 Da over the parent drug, but, in common with Indinavir, ions at m/z 364 and 465. Of most significance is the ion at m/z 465 which indicates that the extra oxygen atom is associated with the indan ring structure. [Pg.251]

There are many similarities between the MS-MS spectra of the (M + H)" " ions of metabolites 2 and 3, with the molecnlar weight of the latter being 16 Da greater than the former. Ions occnr in both spectra at m/z 374 and 273, thns snggesting that this additional oxygen atom has been incorporated into the indan-ring part of the molecnle. [Pg.254]

High molecular weight soluble polymers were not obtained due to cross-linking reactions. These cross-linking reactions involved partial cleavage of the indane ring and multiple acylation reactions [17]. [Pg.567]

The chromane and indane rings in both synthetic brazilin and haematoxylin are considered to be cis fused (ref.115,117). However... [Pg.781]

In particular, the key intermediate product 381 in the synthesis of wighteone was prepared by the oxidative rearrangement of 3 -iodotetraalkoxychalcone 380 [474] and the key step in the synthesis of ( )-indatraline involved the HTIB-promoted diastereoselective ring contraction of a 1,2-dihydronaphthalene 382 to construct the indane ring system 383 (Scheme 3.152) [475]. A similar oxidative rearrangement of 3-cinnamoyl-4-hydroxy-6-methyl-2/7-pyran-2-ones with HTIB in dichloromethane followed by cycliza-tion was used by Prakash and coworkers for the direct conversion of o-hydroxychalcones into isoflavone derivatives [476]. [Pg.211]

On the basis of the possible transition state assembly 123, Ghosh and covrorkers further speculated that the a-chiral center or the indane ring... [Pg.88]


See other pages where Indan ring is mentioned: [Pg.784]    [Pg.251]    [Pg.252]    [Pg.194]    [Pg.195]    [Pg.43]    [Pg.286]    [Pg.119]    [Pg.784]    [Pg.327]    [Pg.370]    [Pg.280]    [Pg.190]    [Pg.37]    [Pg.24]    [Pg.243]    [Pg.755]    [Pg.756]    [Pg.297]    [Pg.181]    [Pg.512]    [Pg.513]    [Pg.501]    [Pg.427]    [Pg.261]    [Pg.288]    [Pg.243]    [Pg.935]    [Pg.223]    [Pg.270]    [Pg.77]    [Pg.1564]   


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Dimerization indan ring

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Indanes, ring systems

Indans—

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