Imine complexes overview

Metallomesogens (continued) examples, 12, 273 imine complexes, 12, 254 pyrimidine complexes, 12, 270 overview, 12, 195-293 via palladacycles, 8, 288 thermotropic liquid crystals, 12, 197 Metalloorganic chemical-vapor deposition, for semiconductor growth, 12, 8... 

Cross-coupling reactions 5-alkenylboron boron compounds, 9, 208 with alkenylpalladium(II) complexes, 8, 280 5-alkylboron boron, 9, 206 in alkyne C-H activations, 10, 157 5-alkynylboron compounds, 9, 212 5-allylboron compounds, 9, 212 allystannanes, 3, 840 for aryl and alkenyl ethers via copper catalysts, 10, 650 via palladium catalysts, 10, 654 5-arylboron boron compounds, 9, 208 with bis(alkoxide)titanium alkyne complexes, 4, 276 carbonyls and imines, 11, 66 in catalytic C-F activation, 1, 737, 1, 748 for C-C bond formation Cadiot-Chodkiewicz reaction, 11, 19 Hiyama reaction, 11, 23 Kumada-Tamao-Corriu reaction, 11, 20 via Migita-Kosugi-Stille reaction, 11, 12 Negishi coupling, 11, 27 overview, 11, 1-37 via Suzuki-Miyaura reaction, 11, 2 terminal alkyne reactions, 11, 15 for C-H activation, 10, 116-117 for C-N bonds via amination, 10, 706 diborons, 9, 167... 

Much work has also been conducted on the hydrosilylation of ketones and imines (Equation 16.16). The products from these reactions are silyl ethers and sdylamines. These additions of silanes across C-X ir-bonds have been conducted predominantly for the purpose of generating optically active alcohols and amines after hydrolysis. Because the mechanism of these reactions is less defined than the mechanism of alkene hydrosilylation, and this chemistry lies outside the theme of this chapter, the hydrosilylation of ketones and imines is presented only briefly. Instead, this chapter provides an overview of the scope and motivation for the hydrosilylation of alkenes and alkynes and provides details on the mechanisms of these reactions catalyzed by complexes of various metals. Several comprehensive reviews of the scope of these reactions have been published. ... 

In recent years, several papers have been published on the combination of an organometaUic catalyst with a chiral phosphonic acid in order to achieve enantioselective reduction of an imine. This obviates the requirement for a Hantzsch base by replacing it with the combination of an organometaUic complex and hydrogen gas. However, since these involve the use of hydrogen gas, they are technically outside the scope of this review, although a recent overview is highlighted [152] and one example is illustrated (Fig. 45) [153]. 

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