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Hypoligated complexes

For hypoligated complexes, either of the following valence-bond procedures is sometimes used to describe the metal-ligand o-bonding ... [Pg.69]

The nature of the spin-state of the metal ion may be reflected in the metal-ligand bond-lengths of the MLj complex. This is well-exemplified for the hyperligated and hypoligated complexes [CoCNHj), and which have... [Pg.71]

Hypoligated transition metal complexes, such as high-spin (5=2) [Fe(H20)6]2+... [Pg.456]

Chapter 5 Pauling 3-Electron Bonds and Hypoligated Transition Metal Complexes... [Pg.67]

The Pauling 3-electron bond theory of hypoligation has wide applicability. All d - d transition-metal complexes of the type will involve one or more Pauling 3-electron bonds in their valence-bond stmctures, if the metal-ion has insufficient vacant inner d and valence-shell s and p orbitals available to form N electron-pair M-L o-bonds with the N ligands. [Pg.72]

See other pages where Hypoligated complexes is mentioned: [Pg.162]    [Pg.163]    [Pg.166]    [Pg.617]    [Pg.457]    [Pg.69]    [Pg.116]    [Pg.240]    [Pg.162]    [Pg.163]    [Pg.166]    [Pg.617]    [Pg.457]    [Pg.69]    [Pg.116]    [Pg.240]    [Pg.165]    [Pg.165]    [Pg.165]    [Pg.166]    [Pg.167]    [Pg.168]    [Pg.169]    [Pg.456]    [Pg.343]    [Pg.67]    [Pg.67]    [Pg.69]    [Pg.72]   
See also in sourсe #XX -- [ Pg.162 ]



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