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Hydrogen peroxide, bond order generation

It seems that the cavities enclose a vapor of the solute because of the high vapor pressure of these compounds. The primary reaction pathway for these compounds appears to be the thermal dissociation in the cavities. The activation energy required to cleave the bond is provided by the high temperature and pressure in the cavitation bubbles. This leads to the generation of radicals such as hydroxyl radical, peroxide radical, and hydrogen radical. These radicals then diffuse to the bulk liquid phase, where they initiate secondary oxidation reactions. The solute molecule then breaks down as a result of free-radical attack. The oxidation of target molecules by free radicals in the bulk liquid phase under normal operating pressures and temperatures can be presented by a second-order rate equation ... [Pg.454]


See other pages where Hydrogen peroxide, bond order generation is mentioned: [Pg.11]    [Pg.291]    [Pg.184]    [Pg.205]    [Pg.188]    [Pg.139]    [Pg.748]    [Pg.620]    [Pg.154]    [Pg.219]    [Pg.69]    [Pg.124]    [Pg.873]    [Pg.60]    [Pg.550]    [Pg.255]   
See also in sourсe #XX -- [ Pg.83 ]




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