Hydrogen chlorine, dipole moment

Phosgene, CI2C=0, has a smaller dipole moment than formaldehyde, H2C=0, even though it contains electronegative chlorine atoms in place of hydrogen. Explain. 

The HC1 molecule Because the electronegativity of chlorine (3.2) is greater than that of hydrogen (2.2), the chlorine is partially negative, and the hydrogen is partially positive. The HCl molecule has a dipole moment oriented as follows ... 

Organic molecules often have polar covalent bonds as a result of unsym-metrical electron sharing caused by difterences in the electronegativity of atoms. For example, a carbon-chlorine bond is polar because chlorine attracts the shared electrons more strongly than carbon does. Carbon-hydrogen bonds are relatively nonpolar. Many molecules as a whole are also polar owing to the cumulative effects of individual polar bonds and electron lone pairs. The polarity of a molecule is measured by its dipole moment, p. 

This is not the case in the CH Cl, molecule. This molecule also has a tetrahedral geometry, but the forces do not cancel out this molecule. The interactions between the carbon and hydrogen atoms are insufficient to cancel the dipoles between carbon and chlorine. As a result, there is a dipole moment for that molecule. 

This molecule is similar to CH4 in that it has an overall tetrahedral shape. However, because not all the bonds are identical, there are three different bond angles HCH, HCCl, and ClCCl. These bond angles are close to, but not equal to, 109.5°. Since chlorine is more electronegative than carbon, which is more electronegative than hydrogen, the bond moments do not cancel and the molecule possesses a dipole moment ... 

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