Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Hydrogen bond basicity defined

The hydrogen-bond donor and acceptor properties of a packing are another dimension of column selectivity. They are independent of the silanol ion-exchange activity described above, and affect the selectivity of a packing in a separate way. We have measured these properties by the relative retention between butylparaben, a hydrogen-bond donor, and dipropylphthalate. The same property, or at least a very similar property, has been called hydrogen bond basicity by Snyder.In our case, it has been defined as follows ... [Pg.117]

The parameters a and p indicate the capacity of a solvent to donate or accept a hydrogen bond from a solute, i.e., the solvent s hydrogen bond acidity or basicity. % is intended to reflect van der Waals-type solute-solvent interactions (dipolar, dispersion, exchange-repulsion, etc.). Equation (43) was subsequently expanded to include a term representing the need to create a cavity for the solute (and thus to interrupt solvent-solvent interactions).188 For this purpose was used the Hildebrand solubility parameter, 5, which is defined as the square root of the solvent s energy of vaporization per unit volume.189 Thus Eq. (43) becomes,190... [Pg.69]

Term defining hydrogen bonding at a basic site... [Pg.49]


See other pages where Hydrogen bond basicity defined is mentioned: [Pg.381]    [Pg.427]    [Pg.162]    [Pg.146]    [Pg.147]    [Pg.443]    [Pg.443]    [Pg.586]    [Pg.591]    [Pg.803]    [Pg.803]    [Pg.14]    [Pg.17]    [Pg.308]    [Pg.381]    [Pg.427]    [Pg.1826]    [Pg.189]    [Pg.54]    [Pg.52]    [Pg.53]    [Pg.60]    [Pg.119]    [Pg.10]    [Pg.28]    [Pg.156]    [Pg.41]    [Pg.323]    [Pg.420]    [Pg.20]    [Pg.110]    [Pg.256]    [Pg.263]    [Pg.5]    [Pg.179]    [Pg.11]    [Pg.16]    [Pg.69]    [Pg.1025]    [Pg.794]    [Pg.37]    [Pg.486]    [Pg.589]    [Pg.263]    [Pg.398]    [Pg.128]   
See also in sourсe #XX -- [ Pg.117 ]




SEARCH



Basicity, hydrogen bonding

Bonding basics

Hydrogen basicity

Hydrogen bond basicity

Hydrogen bonding defined

Hydrogen defined

© 2024 chempedia.info