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Hydration, ionic, structural entropy

The standard molar entropy of hydration of an ion, Ahydr5° , should contain contributions from the formation of the ionic hydration shell and also from the limitation of the ionic rotation of a multiatomic ion in the solution compared with the gas. Hence, such contributions should be deducted, according to Krestov (1962, 1962a), from Ahydr5° in order to obtain the water structural effects of the ion beyond the hydration shell, Astmc (AS ii in the notation of Krestov) ... [Pg.124]

Persson I, Sandstrdm M, YokoyamaH, Chaudhry M (1995) Structure of the solvated strontium and barium ions in aqueous, dimethyl-sulfoxide and pyridine solution, and crystal-structure of strontium and barium hydroxide octahydrate. Z Naturforsch 50 21-37 Schmid R, Miah AM, Sapunov VN (2000) A new table of the thermodynamic quantities of ionic hydration values and some applications (enthtilpy-entropy compensation and Bom radii). Phys Chem Chem Phys 2 97-102... [Pg.379]

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See also in sourсe #XX -- [ Pg.102 , Pg.123 , Pg.124 , Pg.125 , Pg.126 , Pg.129 ]



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Entropy structural

Hydrates, structure

Hydration, ionic entropy

Ionic entropy

Ionic hydrated

Ionic structure

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