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Hybrid materials based porous frameworks

Al-based porous frameworks were also reported to moderately conduct protons above lOO C through the incorporation of imidazole (Im) within the pores. A higher proton-conductive MOF was obtained by introducing adipic acid in a layered oxalate-bridged framework (NH4)2[Zn2(ox)3]-3H20. Also, hybrid materials comprising a MOF and POMs were investigated. ... [Pg.436]

The first part of the book documents the history, structure, chemistry, formulation and characterizations of zeolites in Chapters 1-4. The past 60 years have seen a progression in molecular sieve materials from aluminosilicate zeolites to micro-porous silica polymorphs, microporous aluminophosphate-based polymorphs, metallosihcate and metallophosphate compositions, octahedral-tetrahedral frameworks, mesoporous molecular sieves and, most recently, hybrid metal organic frameworks (MOFs). [Pg.625]

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