Hybrid Intercalation Compounds Containing Perfluoroalkyl Groups

Hybrid Intercalation Compounds Containing Perfluoroalkyl Groups 

Department of Materials Science and Chemistry, Graduate School of Engineering, University ofHyogo, 2167 Shosha Himeji, Hyogo, 671-2201, Japan 

Photophysical properties and photochemical reactions of photoactive organic molecules in solid media may differ from those in homogenous solutions, in terms of the life time of the excited state, efficiency of radiationless quenching, diffusion of excited molecules, etc. [1, 2], Accordingly, the quantum yield of fluorescence, and the distribution and stereochemistry of the photochemical products can be greatly changed. Therefore, the stody of the photoprocesses of organic molecules in solid media is of interest because it could yield various applications such as solid dye laser, nonlinear optics, reaction media for controlled photochemical reactions and so on. 

Various solid materials have been used as hosts of photoactive organic molecules such as zeolties, mesoporous silicas, layered materials, etc. The advantage of layered materials to use as the host materials of photoactive organic molecules is that they possess two-dimensional and expandable interlayer space, which can accommodate a wide variety of 

Functionalized Inorganic Fluorides Synthesis, Characterization Properties ofNanostructured Solids Edited by Alain Tressaud 2010 John Wiley Sons, Ltd 

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Hybrid Intercalation Compounds Containing Perfluoroalkyl Groups... 

Hybrid Intercalation Compounds Containing Perfluoroalkyl Groups 475 15.2.2 Exfoliation and Film Preparation... 

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