Hot electron-induced electrochemiluminescence

Spehar-Deleze AM, Suomi J, Jiang Q, De Rooij N, Koudelka-Hep M, Kulmala S (2006) Heterogeneous oligonucleotide-hybridization assay based on hot electron-induced electrochemiluminescence of a rhodamine label at oxide-coated aluminum and silicon electrodes. Electrochim Acta 51(25) 5438-5444. doi 10.1016/j.electacta.2006.02.017... 

The primary cathodic step of hot electron-induced electrochemiluminescence (HECL) was postulated to be an injection of hot electrons into aqueous electrolyte solution by tunnel emission through an insulating barrier, followed by reduction reactions induced either by presolvated hot electrons or by fully hydrated electrons [37, 38]. The introduction and details of this kind of hot electron electrochemistry and HECL has been reviewed very recently [33] and only short descriptions of the basic features are given here. 

Suomi J, Kulmala S (2009) Hot electron-induced electrochemiluminescence. Reviews in Fluorescence, in press (Chapter 3)... 

Eskola J, Makinen P, Oksa L, Loikas K, Nauma M, Jiang Q, Hakansson M, Suomi J, Kulmala S (2006) Competitive immunoassay by hot electron-induced electrochemiluminescence detection and using a semiautomatic electrochemiluminraneter. J Liunin 118 238-244... 

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See also in sourсe #XX -- [ ]

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