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High-7 . superconductors, defects

A Tripled-Perovskite — Relationship to the New High Tc Oxide Superconductor A tripled cell for the perovskite structure is shown in Figure 33. This structure is closely related to that of the new 90 K superconductor in the following way. The structure of the superconductor can be derived from a highly anion-defect, perovs-kite-type structure. The composition can be obtained as follows. [Pg.87]

Abstract An Eddy current method applying a High Temperature Superconductor ( HTS ) DC SQUID sensor operating at Uquid nitrogen temperature (77K) is presented. The method is developed for the detection of surface or surface near defects. We compare the performance of the SQUID system with the performance gained from a commercial Eddy current system, while using identical probes. The experimental data are obtained on defects in gas turbine blades. The advantage of planar conformable probes for the use with the SQUID is discussed. [Pg.297]

Point defects are also highly prominent in the Tl,Pb,Bi/Ba,Sr,-Ca/Cu/O superconductors. Cation vacancies frequently occur. Some T1 is found on Ca sites, and there is evidence for Ca on the Sr/Ba site. Some Bi is found on both Sr and Ca sites. Both oxygen interstitials and vacancies apparently can occur. Present evidence suggests that compounds with the ideal structures and compositions would not be metallic or superconducting. There are also strong indications that these materials at their ideal compositions are in fact too unstable to be prepared. [Pg.726]

Trivial examples of metastability are solid solutions. Because these are inherently defect systems, they cannot be thermodynamically stable at low temperatures. Most of our high Tc superconductors need to be regarded as solid solutions which are then necessarily metastable phases. We could dismiss this as an irrelevant observation on the basis that solid solutions are merely required in order to adjust the carrier concentration to appropriate levels. However, we seem unable to generally make stable high Tc superconductors. One could even suggest that there is a correlation between Tc and metastability the higher the Tc, the more unstable. [Pg.727]


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High superconductor

Superconductors, high

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