High-alumina tapes

This work was done in collaboration with Professor Hiroshi Yoneyama of Osaka University [124], The procedure used to prepare the LiMu204 tubules is shown schematically in Fig. 21. A commercially available alumina filtration membrane (Anopore, Whatman) was used as the template. Alumina is especially suited for this application because of its high porosity, monodispersity of pore size, and the fact that it can be heated to high temperature without degradation. This membrane contains 200-nm-diameter pores, is 60 p,m thick, and has a porosity of 0.6. A 1.5 cm X 1.5 cm piece of this membrane was mounted on a Pt plate (2 cm X 2 cm) by applying a strip of plastic adhesive tape (also 2 cm X 2 cm NICHIBAN VT-19) across the upper face of the membrane. The Pt plate will serve as the current collector for the LiMn204 battery electrode material. The strip of tape, which will be subsequently removed, had a 1.0 cm circular hole punched in it, which defined the area of the membrane used for the template synthesis of the LiMn204. 

Substrates made by the multilayer process from tape cast alumina have received considerable attention in recent years for multichip module (MCM) applications. An MCM consists of an array of closely packed chips on an interconnect board several inches on a side. Cofired ceramic is attractive relative to organic laminates because its thermal conductivity is almost 2 orders of magnitude higher, an important consideration in high-density circuitry. In addition both alumina and aluminum nitride ceramics are more closely matched to silicon in CTE than are organic boards. For similar reasons, alumina and AIN are attractive for ball grid array (EGA) mounting of chips. ... 

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