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Heavy ketones dimerization

Remarkable progress in the chemistry of main group elements enabled us to synthesize and isolate heavy ketones which are capable of existence as stable species if their highly reactive M=X bond is adequately protected toward dimerization... [Pg.162]

TiCl4 and Mg amalgam. Again, some of these methods use toxic reagents and heavy metals. However, it is known that the dimerization of ketones to 1,2-diols can be accomplished by photochemical methods. These are usually the irradiation of aromatic aldehydes and dialkyl ketones in the presence of a hydrogen donor such as 2-propanol, toluene or amines. °... [Pg.1116]


See other pages where Heavy ketones dimerization is mentioned: [Pg.151]    [Pg.160]    [Pg.208]    [Pg.211]    [Pg.881]    [Pg.888]    [Pg.881]    [Pg.888]    [Pg.5894]    [Pg.5893]    [Pg.208]    [Pg.211]    [Pg.232]    [Pg.29]    [Pg.480]    [Pg.642]   
See also in sourсe #XX -- [ Pg.874 , Pg.875 , Pg.879 , Pg.881 , Pg.882 , Pg.888 ]

See also in sourсe #XX -- [ Pg.874 , Pg.875 , Pg.879 , Pg.881 , Pg.882 , Pg.888 ]




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Heavy ketones

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