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2-halomethyl cycloalkanones

Radical-mediated ring expansion of 2-halomethyl cycloalkanones. [Pg.210]

Bicyclo[n.l.O]alkan-l-oxyl radicals are fleeting intermediates in homolytic reactions of 2-(halomethyl)cycloalkanones and related radical precursors. Unrearranged 2-methyl-cyclohexanone (19) was obtained from treatment of 2-[(phenylselanyl)methyl]cyclohexanone (18) with tributyltin hydride. ... [Pg.2444]

The starting 2-(halomethyl)cycloalkanones 54 (X = Br, I), were easily prepared by treatment of the corresponding cyclic / -oxo esters with base (usually sodium hydride), followed by alkylation with dibromo- or diiodomethane. Yields for the ring expansion were good, and the process worked well, even for 15-membered rings " and large bicycloalkanes. ... [Pg.2481]

See other pages where 2-halomethyl cycloalkanones is mentioned: [Pg.2480]    [Pg.105]    [Pg.2480]   
See also in sourсe #XX -- [ Pg.200 ]

See also in sourсe #XX -- [ Pg.225 ]

See also in sourсe #XX -- [ Pg.200 ]



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