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Grignard reagents, bonding coupling with alkyl halides

Oxidative addition of the carbon-halogen bond is a well-documented reaction for Group 10 transition metal complexes, but it is relatively limited for ruthenium. The example given here involves the reversible oxidative addition of allyl halide to RuCp(CO)2X to produce RuCp(p -allyl)X2 [78]. Oxidative addition of allyl halide to a Ru(0) complex Ru(l,5-COD)(l,3,5-COT) is also reported, but the product yield was poor [79]. Nevertheless, a catalytic Heck-type alkenylation of bromostyrene with methyl acrylate by Ru(l,5-COD)(l,3,5-COT) proceeded smoothly [80]. A cross-coupling reaction of alkenyl halide with Grignard reagents or alkyl lithium also pro-... [Pg.362]

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See also in sourсe #XX -- [ Pg.590 , Pg.599 ]



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Alkyl Bonds

Alkyl Grignard reagents

Alkyl Grignards

Alkyl coupling

Alkyl halides bonding

Alkyl reagents

Alkylating reagents

Alkylation with alkyl halides

Coupling reagent

Coupling with Grignards

Coupling with alkyl halides

Couplings alkylative

Grignard coupling

Grignard reagents coupling

Grignard reagents with halides

Grignard reagents, bonding

Grignard reagents, bonding alkyl halides

Grignard reagents, bonding halide

Grignard with halides

Halide bond

Halides reagents

Halides, alkyl coupling with Grignard reagents

Reagent alkyl halides

Reagents alkylation

With Grignard Reagents

With alkyl halides

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