Graphite electrocatalyst-coated

A similar catalytic activity with a monomeric porphyrin of iridium has been observed when adsorbed on a graphite electrode.381-383 It is believed that the active catalyst on the surface is a dimeric species formed by electrochemical oxidation at the beginning of the cathodic scan, since cofacial bisporphyrins of iridium are known to be efficient electrocatalysts for the tetraelectronic reduction of 02. In addition, some polymeric porphyrin coatings on electrode surfaces have been also reported to be active electroactive catalysts for H20 production, especially with adequately thick films or with a polypyrrole matrix.384-387... 

Thirty five years later it must be admitted that fuel cell technology has not lived up to many of the early expectations. The most important stumbling block has been the development of an inexpensive electrocatalyst,. suitable for work in acid solution over long periods of time. Catalysts consisting of large-surface-area graphite, coated with small amounts of platinum and bonded with Teflon, have been developed... 

A variant of the enhanced reaction zone concept is to utilize as catalyst support various porous three-dimensional electrodes with thickness between 200 to 2,000 pm. Thus, the electric contact resistance between the individual layers is eliminated. The three-dimensional matrix (such as various graphite felts, reticulated vitreous carbon, metal mesh, felt, and foam) supporting uniformly dispersed electrocatalysts (nanoparticles or thin mesoporous coating) could assure an extended reaction zone for fuel (methanol, ethanol, and formie aeid) electrooxidation, providing an ionic conductor network is established to link the catalytically active sites and the proton exchange membrane. The patent by Wilkinson et al. also suggests such electrode configurations (e.g., carbon foam, expended metal and reticulated metal) but experimental results were not provided [303]. 

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