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Gomberg-Bachmann pinacol synthesis

Diols (pinacols) can be synthesized by reduction of aldehydes and ketones with active metals such as sodium, magnesium, or aluminum. Aromatic ketones give better yields than aliphatic ones. The use of a Mg—Mgl2 mixture has been called the Gomberg-Bachmann pinacol synthesis. As with a number of other reactions involving sodium, there is a direct electron transfer here, converting the ketone or aldehyde to a ketyl, which dimerizes. [Pg.1560]

B. P. Mundy, D. R. Bruss, Y. Kim, R. D. Larsen, R. J. Wamet, Tetrahedron Letters 1985,26, 3927 Gomberg-Bachmann Pinacol Synthesis... [Pg.512]

Other references related to the Gomberg-Bachmann pinacol synthesis are cited in the literature." ... [Pg.1247]

Gomberg-Bachmann pinacol synthesis 1, 689 Gomberg reaction, improved 16, 842... [Pg.324]

See other pages where Gomberg-Bachmann pinacol synthesis is mentioned: [Pg.1245]    [Pg.1245]    [Pg.1246]    [Pg.170]    [Pg.1245]    [Pg.1245]    [Pg.1246]    [Pg.170]    [Pg.90]   
See also in sourсe #XX -- [ Pg.928 , Pg.1560 ]

See also in sourсe #XX -- [ Pg.512 ]

See also in sourсe #XX -- [ Pg.1854 ]

See also in sourсe #XX -- [ Pg.512 ]



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Gomberg

Gomberg-Bachmann

Gomberg-Bachmann pinacol

Pinacol

Pinacolate

Pinacolation

Pinacolizations

Pinacols

Pinacols, synthesis

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